Surface hydration and cationic sites of nanohydroxyapatites with amorphous or crystalline surfaces: a comparative study (Articolo in rivista)

Type
Label
  • Surface hydration and cationic sites of nanohydroxyapatites with amorphous or crystalline surfaces: a comparative study (Articolo in rivista) (literal)
Anno
  • 2010-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/jp105971s (literal)
Alternative label
  • Sakhno Yuriy; Bertinetti Luca; Iafisco Michele; Tampieri Anna; Roveri Norberto; Martra Gianmario (2010)
    Surface hydration and cationic sites of nanohydroxyapatites with amorphous or crystalline surfaces: a comparative study
    in Journal of physical chemistry. C
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Sakhno Yuriy; Bertinetti Luca; Iafisco Michele; Tampieri Anna; Roveri Norberto; Martra Gianmario (literal)
Pagina inizio
  • 16640 (literal)
Pagina fine
  • 16648 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://pubs.acs.org/doi/abs/10.1021/jp105971s (literal)
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  • 114 (literal)
Rivista
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  • In: Journal of Physical Chemistry C, vol. 114 pp. 16640 - 16648. ©American Chemical Society, 2010. (literal)
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  • 39 (literal)
Note
  • ISI Web of Science (WOS) (literal)
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  • Dipartimento di Chimica IFM & Centro di Eccellenza Interdipartimentale \"NIS\", Universita? di Torino, Via P. Giuria 7, 10125 Torino, Italy; Dipartimento di Chimica \"G. Ciamician\", Universita? di Bologna, Via Selmi 2, 40126 Bologna, Italy; Dipartimento di Scienze Mediche, Universita? del Piemonte Orientale, Via Solaroli 4, 28100 Novara, Italy; ISTEC-CNR, Via Granarolo 64, 48018 Faenza, Italy (literal)
Titolo
  • Surface hydration and cationic sites of nanohydroxyapatites with amorphous or crystalline surfaces: a comparative study (literal)
Abstract
  • This paper is an extension of previous work devoted to the characterization of platelet-like hydroxyapatite (HA) nanoparticles constituted by a crystalline core coated by an amorphous surface layer 1-2 nm thick (Bertinetti et al. J. Phys. Chem. C. 2007, 111, 4027-4035). By increasing the preparation temperature, the platelet morphology was retained but HA nanoparticles exhibited a higher degree of crystallinity (evaluated by X-ray diffractometry). High-resolution transmission electron microscopy revealed that, in this case, the crystalline order was extended up to the particles' surfaces, which were of the (010), (100), and (001) types. IR spectroscopy was used to investigate the surface hydration of both materials, in terms of adsorbed H2O molecules and surface hydroxy groups, as well as the Lewis acidity of surface cations, by removing water and adsorbing CO. For both features, strong similarities between amorphous and crystalline surfaces were found (literal)
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