Malayaite Ceramic Pigments: a Combined Optical Spectroscopy and Neutron/X-ray Diffraction Study (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Malayaite Ceramic Pigments: a Combined Optical Spectroscopy and Neutron/X-ray Diffraction Study (Articolo in rivista) (literal)

Anno

• 2009-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.materresbull.2009.03.006 (literal)

Alternative label

• Giuseppe Cruciani.; Michele Dondi; Matteo Ardit ; Teodora Stoyanova Lyubenova; Juan B. Carda ; Francesco Matteucci ; Anna Luisa Costa (2009)
  Malayaite Ceramic Pigments: a Combined Optical Spectroscopy and Neutron/X-ray Diffraction Study
  in Materials research bulletin
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Giuseppe Cruciani.; Michele Dondi; Matteo Ardit ; Teodora Stoyanova Lyubenova; Juan B. Carda ; Francesco Matteucci ; Anna Luisa Costa (literal)

Pagina inizio

• 1778 (literal)

Pagina fine

• 1785 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.sciencedirect.com/science/article/pii/S0025540809000889 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 44 (literal)

Rivista

• Materials research bulletin (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• In: Materials Research Bulletin, vol. 44 pp. 1778 - 1785. Elsevier Ltd, 2009. (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Cruciani, Ardit: Department of Earth Sciences, University of Ferrara Dondi, Matteucci, Costa: CNR-ISTEC, Faenza Stoyanova Lyubenova, Carda: Dept of Inorganic and Organic Chemistry, University Jaime I Castellon (literal)

Titolo

• Malayaite Ceramic Pigments: a Combined Optical Spectroscopy and Neutron/X-ray Diffraction Study (literal)

Abstract

• Ceramic pigments based on the Cr-doped malayaite structure were synthesized by solid state reaction and characterized by optical spectroscopy and combined X-ray and neutron powder diffraction in order to elucidate the still unclear chromium substitution mechanisms. The results show that coloration is actually due to simultaneous occurrence of Cr4+ and Cr3+ ions in the crystal lattice. Spectroscopy data confirm that Cr4+ is replacing Sn4+ in the octahedral site and, in minor amount, Si4+ in the tetrahedral site. In addition, neutron powder diffraction data suggest that Cr3+ substitution for octahedral Sn4+ is charge balanced by formation of oxygen vacancies with no preference over the different oxygen sites. Upon incorporation of Cr ion, the SnO6 octahedra exhibit an off-centre displacement of central cation which in turn induces a rearrangement of both the octahedral and tetrahedral coordination shells. (literal)

Prodotto di

• Sviluppo materiali e sistemi ceramici per edilizia, usi domestici e industriali (SP.P01.010.001) (Modulo)
• Institute of science and technology for ceramics (ISTEC) (Istituto)

Autore CNR

• ANNA LUISA COSTA (Persona)
• FRANCESCO MATTEUCCI (Persona)
• MICHELE DONDI (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Malayaite Ceramic Pigments: a Combined Optical Spectroscopy and Neutron/X-ray Diffraction Study" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of science and technology for ceramics (ISTEC) (Istituto)
• Sviluppo materiali e sistemi ceramici per edilizia, usi domestici e industriali (SP.P01.010.001) (Modulo)

Autore CNR di

• MICHELE DONDI (Unità di personale interno)
• FRANCESCO MATTEUCCI (Persona)
• ANNA LUISA COSTA (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Materials research bulletin (Rivista)

Insieme di parole chiave di

• Parole chiave di "Malayaite Ceramic Pigments: a Combined Optical Spectroscopy and Neutron/X-ray Diffraction Study" (Insieme di parole chiave)