Pd/SiO2 as heterogeneous catalyst for the Heck reaction: evidence for a sensitivity to the surface structure of supported particles (Articolo in rivista)

Type
Label
  • Pd/SiO2 as heterogeneous catalyst for the Heck reaction: evidence for a sensitivity to the surface structure of supported particles (Articolo in rivista) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Alternative label
  • Martra G.; Bertinetti L.; Gerbaldi C.; Maggi R.; Sartori G.; Coluccia S. (2009)
    Pd/SiO2 as heterogeneous catalyst for the Heck reaction: evidence for a sensitivity to the surface structure of supported particles
    in Catalysis letters
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Martra G.; Bertinetti L.; Gerbaldi C.; Maggi R.; Sartori G.; Coluccia S. (literal)
Pagina inizio
  • 50 (literal)
Pagina fine
  • 57 (literal)
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  • 132 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • In: Catalysis Letters, vol. 132 (1-2) pp. 50 - 57. SPRINGER, 233 SPRING ST, NEW YORK, NY 10013 USA, 2009. (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Univ Turin, Dept IPM Chem, I-10125 Turin, Italy, Univ Parma, Dept Organ & Ind Chem, Clean Synthet Methodol Grp, I-43100 Parma, Italy (literal)
Titolo
  • Pd/SiO2 as heterogeneous catalyst for the Heck reaction: evidence for a sensitivity to the surface structure of supported particles (literal)
Abstract
  • The contact of Pd(AcO)(2) in solution with thiouric tethered to a silica led to the formation of supported nanoparticles (ca. 2 nm in size) active in the Heck reaction, quite sensitive to the palladium leaching. A stable supported phase was obtained by subsequent calcination, but the catalytic activity resulted strongly dependent on the calcination temperature. Such a behaviour was related to differences in the surface structure of the supported particles, as those monitored by IR spectroscopy of CO adsorbed on catalysts reduced at various temperatures (literal)
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