Coagulation and carbonization processes in slightly sooting premixed flames (Articolo in rivista)

Type
Label
  • Coagulation and carbonization processes in slightly sooting premixed flames (Articolo in rivista) (literal)
Anno
  • 2002-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/S1540-7489(02)80291-7 (literal)
Alternative label
  • Basile, G; Rolando, A; D'Alessio, A; D'Anna, A; Minutolo, P (2002)
    Coagulation and carbonization processes in slightly sooting premixed flames
    in Proceedings of the Combustion Institute
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Basile, G; Rolando, A; D'Alessio, A; D'Anna, A; Minutolo, P (literal)
Pagina inizio
  • 2391 (literal)
Pagina fine
  • 2397 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://www.sciencedirect.com/science/article/pii/S1540748902802917 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 29 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 2 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Dipartimento di Ingegneria Chimica Università di Napoli \"Federico II\" Ple Tecchio 80 80125 Napoli, Italy Istituto di Ricerche sulla Combustione CNR Ple Tecchio 80 80125 Napoli, Italy (literal)
Titolo
  • Coagulation and carbonization processes in slightly sooting premixed flames (literal)
Abstract
  • UV absorption spectra in the 200-400 nm range and transient thermocouple measurements are used tocharacterize the process of nanoparticle formation and their carbonization to soot particles in slightly sooting premixed flames of ethylene. The UV absorption technique allows a quantitative determination of the concentration of both soot and nanoparticles. In the examined flame, the total particulate is initially present as nanoparticles, but even in the sooting region, where the yellow luminosity is dominant, soot particles represent less than 50% of the total mass of particulate. This technique can be easily used for the determination of soot and nanoparticles at the exhaust of real combustion devices and in urban polluted areas. Time-resolved thermocouple measurements are used to follow the variation along the flame axis of the emissivity of the particulate deposited by thermophoresis on the thermocouple junction. Thesevalues are used for the evaluation of an apparent rate of carbonization, which has been compared with the coagulation rate of the particles evaluated by scattering and extinction measurements. Both processes, carbonization and coagulation, show a second-order kinetic with a constant of the order of 5×1012 cm3/s. This technique has shown to be a very simple method for detecting nanoparticles, which can be applied also in diffusion flames and other practical systems. In addition, it furnishes emissivity values, which might be useful for a more realistic assessment of the radiative heat transfer of slightly luminous flames. (literal)
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