Rh-La(Mn,Co)O3 monolithic catalysts for the combustion of methane under fuel-rich conditions (Articolo in rivista)

Type
Label
  • Rh-La(Mn,Co)O3 monolithic catalysts for the combustion of methane under fuel-rich conditions (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Alternative label
  • Cimino S., Landi G., Lisi L., Russo, G. (2006)
    Rh-La(Mn,Co)O3 monolithic catalysts for the combustion of methane under fuel-rich conditions
    in Catalysis Today
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Cimino S., Landi G., Lisi L., Russo, G. (literal)
Pagina inizio
  • 454 (literal)
Pagina fine
  • 461 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 117 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 4 (literal)
Note
  • Scopus (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Istituto di Ricerche sulla Combustione IRC-CNR Dipartimento di Ingegneria Chimica - Università Federico II Napoli (literal)
Titolo
  • Rh-La(Mn,Co)O3 monolithic catalysts for the combustion of methane under fuel-rich conditions (literal)
Abstract
  • Novel Rh-La(Mn,Co)O3 structured catalysts were developed for the partial oxidation of methane to syngas intended as a preliminary conversion step in combustion systems such as power turbines and utility burners employing a fuel-rich fuel-lean approach to reduce NOx formation. Active components were impregnated on La-g-Al2O3 washcoated honeycomb monoliths and the catalysts were characterised by BET, SEM/EDS, H2-TPR, and in situ FT-IR under reaction conditions. Catalytic partial oxidation of methane was tested under both pseudo-isothermal and pseudo-adiabatic conditions showing that the process can be conducted with high yield and selectivity: improved and stable performances were found especially in the case of Rh-LaMnO3 catalyst, due to the synergism between active sites and to the stabilization of the noble metal. (literal)
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