ION CHROMATOGRAPHY/ELECTROSPRAY MASS SPECTROMETRY FOR THE IDENTIFICATION OF LOW-MOLECULAR-WEIGHT ORGANIC ACIDS DURING THE 2,4-DICHLORO-PHENOL DEGRADATION (Articolo in rivista)

Type
Label
  • ION CHROMATOGRAPHY/ELECTROSPRAY MASS SPECTROMETRY FOR THE IDENTIFICATION OF LOW-MOLECULAR-WEIGHT ORGANIC ACIDS DURING THE 2,4-DICHLORO-PHENOL DEGRADATION (Articolo in rivista) (literal)
Anno
  • 2005-01-01T00:00:00+01:00 (literal)
Alternative label
  • MASCOLO G., LOPEZ A., DETOMASO A., LOVECCHIO G. (2005)
    ION CHROMATOGRAPHY/ELECTROSPRAY MASS SPECTROMETRY FOR THE IDENTIFICATION OF LOW-MOLECULAR-WEIGHT ORGANIC ACIDS DURING THE 2,4-DICHLORO-PHENOL DEGRADATION
    in Journal of chromatography (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • MASCOLO G., LOPEZ A., DETOMASO A., LOVECCHIO G. (literal)
Pagina inizio
  • 191 (literal)
Pagina fine
  • 196 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 1067 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Consiglio Nazionale delle Ricerche, Istituto di Ricerca Sulle Acque, Via F. De Blasio 5, 70123 Bari, Italy (literal)
Titolo
  • ION CHROMATOGRAPHY/ELECTROSPRAY MASS SPECTROMETRY FOR THE IDENTIFICATION OF LOW-MOLECULAR-WEIGHT ORGANIC ACIDS DURING THE 2,4-DICHLORO-PHENOL DEGRADATION (literal)
Abstract
  • End-product identification of organic pollutants during oxidation water treatments is of environmental concern due to their potential toxicity. In this work the coupling of ion chromatography (IC), equipped with a membrane ion suppressor, and electrospray ionization mass spectrometry (ESI-MS) has been successfully exploited for the identification of novel low molecular weight organic acids formed as final by-products of 2,4-dichloro-phenol (DCP) degradation by Fenton's reagent, an oxidation method widely employed to degrade recalcitrant organic pollutants in industrial wastewater. The IC-ESI-MS analytical set-up not only allowed the detection of known organic acids but also the identification of 13 new low molecular weight organic acids as a result of extensive oxidation of the parent organic pollutant. Some of the novel organic acids were shown to be chlorine containing by-products and, consequently, of environmental concern. The analytical set-up could be used for characterizing the unknown organic carbon fraction arising from oxidation water treatments. © 2004 Elsevier B.V. All rights reserved. (literal)
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