CHARACTERIZATION OF CARBOFURAN PHOTODEGRADATION BY-PRODUCTS BY LIQUID CHROMATOGRAPHY/HYBRID QUADRUPOLE TIME-OF-FLIGHT/MASS SPECTROMETRY (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• CHARACTERIZATION OF CARBOFURAN PHOTODEGRADATION BY-PRODUCTS BY LIQUID CHROMATOGRAPHY/HYBRID QUADRUPOLE TIME-OF-FLIGHT/MASS SPECTROMETRY (Articolo in rivista) (literal)

Anno

• 2005-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/rcm.2036 (literal)

Alternative label

• DETOMASO A., MASCOLO G., LOPEZ A. (2005)
  CHARACTERIZATION OF CARBOFURAN PHOTODEGRADATION BY-PRODUCTS BY LIQUID CHROMATOGRAPHY/HYBRID QUADRUPOLE TIME-OF-FLIGHT/MASS SPECTROMETRY
  in RCM. Rapid communications in mass spectrometry
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• DETOMASO A., MASCOLO G., LOPEZ A. (literal)

Pagina inizio

• 2193 (literal)

Pagina fine

• 2202 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 19 (literal)

Rivista

• RCM. Rapid communications in mass spectrometry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Instituto di Ricerca Sulle Acque, C.N.R., Sezione di Bari, Via F. De Blasio 5, 70123 Bari, Italy (literal)

Titolo

• CHARACTERIZATION OF CARBOFURAN PHOTODEGRADATION BY-PRODUCTS BY LIQUID CHROMATOGRAPHY/HYBRID QUADRUPOLE TIME-OF-FLIGHT/MASS SPECTROMETRY (literal)

Abstract

• The structural elucidation of by-products arising from carbofuran photodegradation using a highpressure UV lamp has been investigated by liquid chromatography/electrospray ionization tandem mass spectrometry (LC/ESI-MS/MS) employing a quadrupole time-of-flight mass spectrometer. Exact mass measurements of the [MþH]þ ions of the by-products and of product ions allowed the elemental formulae and related structures of seven photodegradation by-products (resulting, respectively, from photo-Fries rearrangement, hydroxylation of the benzene ring, oxidation of the 2,3-dihydrobenzofuran ring, cleavage of the carbamate group, hydrolysis of the ether group and the newly observed radical coupling and decarboxylation processes) to be determined confidently. Accurate mass measurements of product ions allowed ambiguities to be removed concerning neutral losses having the same nominal mass, namely CO and C2H4, allowing the fragmentation patterns to be rationalized. (literal)

Prodotto di

• Water research institute (IRSA) (Istituto)
• Sviluppo di nuovi processi di controllo dell'inquinamento idrico. (TA.P07.002.002) (Modulo)

Autore CNR

• ANTONIO LOPEZ (Unità di personale interno)
• GIUSEPPE MASCOLO (Unità di personale interno)
• ANTONIA DETOMASO (Unità di personale interno)

Incoming links:

Prodotto

• Water research institute (IRSA) (Istituto)
• Sviluppo di nuovi processi di controllo dell'inquinamento idrico. (TA.P07.002.002) (Modulo)

Autore CNR di

• ANTONIO LOPEZ (Unità di personale interno)
• ANTONIA DETOMASO (Unità di personale interno)
• GIUSEPPE MASCOLO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• RCM. Rapid communications in mass spectrometry (Rivista)