Patchy Multishell Segregation in Pd-Pt Alloy Nanoparticles (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Patchy Multishell Segregation in Pd-Pt Alloy Nanoparticles (Articolo in rivista) (literal)

Anno

• 2011-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/nl200322s (literal)

Alternative label

• Barcaro G., Fortunelli A., Polak M., Rubinovich L. (2011)
  Patchy Multishell Segregation in Pd-Pt Alloy Nanoparticles
  in Nano letters (Print); ACS, American chemical society, Washington, DC (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Barcaro G., Fortunelli A., Polak M., Rubinovich L. (literal)

Pagina inizio

• 1766 (literal)

Pagina fine

• 1769 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 11 (literal)

Rivista

• Nano letters (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 4 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• CNR-IPCF (literal)

Titolo

• Patchy Multishell Segregation in Pd-Pt Alloy Nanoparticles (literal)

Abstract

• Chemical ordering in face-centered-cubic-like PdPt nanoparticles consisting of 38-201 atoms is studied via density-functional calculations combined with a symmetry orbit approach. It is found that for larger particles in the Pd-rich regime, Pt atoms can segregate at the center of the nanoparticle (111) surface facets, in contrast with extended systems in which Pd is known to segregate at the surface of alloy planar surfaces. In a range of compositions around 1:1, a novel multishell chemical ordering pattern was favored, in which each shell is a patchwork of islands of atoms of the two elements, but the order of the patchwork is reversed in the alternating shells. These findings are rationalized in terms of coordination-dependent bondenergy variations in the metal-metal interactions, and their implications in terms of properties and applications of nanoscale alloy particles are discussed. (literal)

Editore

• ACS, American chemical society (Editore)

Prodotto di

• Sviluppo ed applicazione di modelli e metodi anche multiscala per lo studio di nanosistemi e nanostrutture. (MD.P01.026.008) (Modulo)
• Istituto per i processi chimico-fisici (IPCF) (Istituto)

Autore CNR

• GIOVANNI BARCARO (Persona)
• ALESSANDRO FORTUNELLI (Persona)

Incoming links:

Prodotto

• Istituto per i processi chimico-fisici (IPCF) (Istituto)
• Sviluppo ed applicazione di modelli e metodi anche multiscala per lo studio di nanosistemi e nanostrutture. (MD.P01.026.008) (Modulo)

Autore CNR di

• ALESSANDRO FORTUNELLI (Persona)
• GIOVANNI BARCARO (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Nano letters (Rivista)

Editore di

• ACS, American chemical society (Editore)