http://www.cnr.it/ontology/cnr/individuo/prodotto/ID4043
Ab initio study of the EFG at the N sites in imidazole (Articolo in rivista)
- Type
- Label
- Ab initio study of the EFG at the N sites in imidazole (Articolo in rivista) (literal)
- Anno
- 2008-01-01T00:00:00+01:00 (literal)
- Alternative label
Goncalves, MB; Di Felice, R; Poleshchuk, OK; Petrilli, HM (2008)
Ab initio study of the EFG at the N sites in imidazole
in Hyperfine interactions
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Goncalves, MB; Di Felice, R; Poleshchuk, OK; Petrilli, HM (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- \"[Goncalves, Marcos Brown; Petrilli, H. M.] Univ Sao Paulo, Inst Fis, BR-05315970 Sao Paulo, Brazil; [Di Felice, R.] Univ Modena & Reggio E, Dip Fis, CNR, INFM,Natl Ctr Nanostruct & Biosyst Surfaces S3, I-41100 Modena, Italy; [Poleshchuk, O. Kh.] Tomsk State Pedag Univ, Tomsk 634041, Russia (literal)
- Titolo
- Ab initio study of the EFG at the N sites in imidazole (literal)
- Abstract
- We study the nuclear quadrupole interaction at the nitrogen sites in the molecular and crystalline phases of the imidazole compound. We use PAW which is a state-of-the-art method to calculate the electronic structure and electric field gradient at the nucleus in the framework of the density functional theory. The quadrupole frequencies at both imino and amino N sites are in excellent agreement with measurements. This is the first time that the electric field gradient at crystalline imidazole is correctly treated by an ab initio theoretical approach. (literal)
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