Novel (glycerol)borate-based ionic liquids: an experimental and theoretical study (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Novel (glycerol)borate-based ionic liquids: an experimental and theoretical study (Articolo in rivista) (literal)

Anno

• 2010-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/jp100809x (literal)

Alternative label

• Chiappe C, Signori F, Valentini G, Marchetti L, Pomelli CS, Bellina F. (2010)
  Novel (glycerol)borate-based ionic liquids: an experimental and theoretical study
  in The journal of physical chemistry. B (1997 : Online); American Chemical Society, Washington (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Chiappe C, Signori F, Valentini G, Marchetti L, Pomelli CS, Bellina F. (literal)

Pagina inizio

• 5082 (literal)

Pagina fine

• 5088 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 114 (literal)

Rivista

• ?The ?journal of physical chemistry. B (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Dipartimento di Chimica e Chimica Industriale, UniVersita di Pisa, Via Risorgimento 35, 56126 Pisa, Italy IPCF-CNR, Area della Ricerca di Pisa, via Moruzzi 1, 56100 Pisa Italy (literal)

Titolo

• Novel (glycerol)borate-based ionic liquids: an experimental and theoretical study (literal)

Abstract

• A series of newly designed (glycerol)borate based ionic liquids were synthesized and characterized. The synthesis of these ionic liquids involves, first, the preparation of the bis(glycerol)boric acid(s) followed by neutralization with the appropriate base, [cat]OH. Ionic liquids bearing inorganic (Li+, Na+, K+) or organic cations have been prepared and characterized. The ability of the bis(glycerol)borate anions to undergo dissociation reaction in the presence of water, depending on cation nature, was investigated by NMR. Theoretical calculations were also performed to evaluate the relative stability of the possible bis(glycerol)borate isomers as nude ions or as ion pairs with Li+, Na+, and H+. Important information about the structural features of H[Gly2B] useful to rationalize the chemical behavior have been obtained. (literal)

Editore

• American Chemical Society (Editore)

Prodotto di

• MD.P01.017.001 Film di materiali polimerici: effett di confinamento superficiale ed applicazioni (MD.P01.017.002) (Modulo)
• Istituto per i processi chimico-fisici (IPCF) (Istituto)

Autore CNR

• FRANCESCA SIGNORI (Unità di personale interno)

Incoming links:

Prodotto

• Istituto per i processi chimico-fisici (IPCF) (Istituto)
• MD.P01.017.001 Film di materiali polimerici: effett di confinamento superficiale ed applicazioni (MD.P01.017.002) (Modulo)

Autore CNR di

• FRANCESCA SIGNORI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• ?The ?journal of physical chemistry. B (Rivista)

Editore di

• American Chemical Society (Editore)