Functionalized copper-phthalocyanine in solution and as thin film: photochemical and morphological characterization towards applications (Articolo in rivista)

Type
Label
  • Functionalized copper-phthalocyanine in solution and as thin film: photochemical and morphological characterization towards applications (Articolo in rivista) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/la9010955 (literal)
Alternative label
  • Chiara Ingrosso,+,? M. Lucia Curri,? Paola Fini,? Gabriele Giancane,§ Angela Agostiano,+,? and Ludovico Valli*,§ (2009)
    Functionalized copper-phthalocyanine in solution and as thin film: photochemical and morphological characterization towards applications
    in Langmuir
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Chiara Ingrosso,+,? M. Lucia Curri,? Paola Fini,? Gabriele Giancane,§ Angela Agostiano,+,? and Ludovico Valli*,§ (literal)
Pagina inizio
  • 10305 (literal)
Pagina fine
  • 10313 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 25 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
  • Scopus (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • +Dipartimento di Chimica, Università di Bari, via Orabona 4, I-70126 Bari, Italy, ?CNR-IPCF Sez. Bari c/o Dipartimento di Chimica, Università di Bari, Italy, and §Università del Salento, Dipartimento di Ingegneria dell'Innovazione, via Monteroni, 73100 Lecce, Italy (literal)
Titolo
  • Functionalized copper-phthalocyanine in solution and as thin film: photochemical and morphological characterization towards applications (literal)
Abstract
  • This article reports on an extensive investigation on a functionalized phthalocyanine, namely, copper(II) tetrakis- (isopropoxy-carbonyl)-phthalocyanine (TIPCuPc). The self-association of the molecules is extensively described in solution in different solvents (DMSO, DMF, CHCl3, pyridine) by means ofUV-vis steady state spectroscopy at the air/ water interface by Brewster angle microscopy (BAM) and in thin films by using atomic force microscopy (AFM). We investigated the morphology of TIPCuPc as thin film by evaluating different factors: temperature, solvent, concentration, transferring procedure (spin-coating and Langmuir-Scha¨ fer technique), and nature of the substrate (mica and quartz). The behavior of the molecules underUVlight irradiation and their thermal stability were studied as well. Such a detailed study can allow a suitable processing of this phthalocyanine derivative for future applications. Here the photoelectrochemical activity of the phthalocyanine was investigated when suitably combined as sensitizer with rodlike TiO2 nanocrystals (NCs) in hybrid junctions integrated in a photoelectrochemical cell. (literal)
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