Comments on the paper: “Accurate quantitative analysis of gold alloys using multi-pulse laser-induced breakdown spectroscopy and a correlation-based calibration method” (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Comments on the paper: “Accurate quantitative analysis of gold alloys using multi-pulse laser-induced breakdown spectroscopy and a correlation-based calibration method” (Articolo in rivista) (literal)

Anno

• 2009-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.sab.2009.03.005 (literal)

Alternative label

• Cristoforetti G., Legnaioli S., Palleschi V., Tognoni E. (2009)
  Comments on the paper: “Accurate quantitative analysis of gold alloys using multi-pulse laser-induced breakdown spectroscopy and a correlation-based calibration method”
  in Spectrochimica acta. Part B, Atomic spectroscopy
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Cristoforetti G., Legnaioli S., Palleschi V., Tognoni E. (literal)

Pagina inizio

• 357 (literal)

Pagina fine

• 358 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 64 (literal)

Rivista

• Spectrochimica acta. Part B, Atomic spectroscopy (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• IPCF-CNR (literal)

Titolo

• Comments on the paper: “Accurate quantitative analysis of gold alloys using multi-pulse laser-induced breakdown spectroscopy and a correlation-based calibration method” (literal)

Abstract

• The problem of finding new methods for the analysis of precious alloys has stimulated, in recent years, a number of different proposals for improving the analytical procedures introducing more robust calibration (or calibration-free) methods. In the paper \"Accurate quantitative analysis of gold alloys using multi-pulse laser-induced breakdown spectroscopy and a correlation-based calibration method\" by G. Galbacs, N. Jedinski, G.Cseh, Z. Galbacs and L. Turi [Spectrochimica Acta Part B, Volume 63, Issue 5, 591-597 (May 2008)] the authors proposed the use of multiple-pulse LIBS and a correlation-based method for building calibration curves for quantitative analysis of gold alloys. The method is proposed for gold alloys prepared using a fixed proportion of the alloying element. The general case where the relative concentration of the elements of the matrix is not a priori known is not discussed in the paper. In this communication, we will demonstrate that the method proposed is extremely fragile against matrix effects, and therefore cannot be usefully applied for the purpose of actual analytical measurements on gold alloys without a previous knowledge of the matrix composition. (literal)

Prodotto di

• Dinamica di plasmi e laser-plasmi (MD.P03.028.001) (Modulo)
• Istituto per i processi chimico-fisici (IPCF) (Istituto)

Autore CNR

• GABRIELE CRISTOFORETTI (Persona)
• STEFANO LEGNAIOLI (Unità di personale interno)
• ELISABETTA TOGNONI (Unità di personale interno)
• VINCENZO PALLESCHI (Unità di personale interno)

Incoming links:

Prodotto

• Istituto per i processi chimico-fisici (IPCF) (Istituto)
• Dinamica di plasmi e laser-plasmi (MD.P03.028.001) (Modulo)

Autore CNR di

• VINCENZO PALLESCHI (Unità di personale interno)
• GABRIELE CRISTOFORETTI (Persona)
• ELISABETTA TOGNONI (Unità di personale interno)
• STEFANO LEGNAIOLI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Spectrochimica acta. Part B, Atomic spectroscopy (Rivista)