In-situ X-ray photoelectron spectroscopy study of catalyst-support interactions and growth of carbon nanotube forests (Articolo in rivista)

Type
Label
  • In-situ X-ray photoelectron spectroscopy study of catalyst-support interactions and growth of carbon nanotube forests (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/jp802474g (literal)
Alternative label
  • Mattevi, C; Wirth, CT; Hofmann, S; Blume, R; Cantoro, M; Ducati, C; Cepek, C; Knop-Gericke, A; Milne, S; Castellarin-Cudia, C; Dolafi, S; Goldoni, A; Schloegl, R; Robertson, J (2008)
    In-situ X-ray photoelectron spectroscopy study of catalyst-support interactions and growth of carbon nanotube forests
    in Journal of physical chemistry. C
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Mattevi, C; Wirth, CT; Hofmann, S; Blume, R; Cantoro, M; Ducati, C; Cepek, C; Knop-Gericke, A; Milne, S; Castellarin-Cudia, C; Dolafi, S; Goldoni, A; Schloegl, R; Robertson, J (literal)
Pagina inizio
  • 12207 (literal)
Pagina fine
  • 12213 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 112 (literal)
Rivista
Note
  • Scopus (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • \"[Wirth, Christoph Tobias; Hofmann, Stephan; Milne, Stuart; Robertson, John] Univ Cambridge, Dept Engn, Cambridge CB3 0FA, England; [Mattevi, Cecilia; Cepek, Cinzia] Lab Nazl TASC CNR INFM, I-34012 Trieste, Italy; [Blume, Raoul; Knop-Gericke, Axel; Schloegl, Robert] Fritz Haber Inst, D-14195 Berlin, Germany; [Cantoro, Mirco] IMEC, B-3001 Louvain, Belgium; [Ducati, Caterina] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England; [Castellarin-Cudia, Carla; Dolafi, Sheema; Goldoni, Andrea] Sincrotrone Trieste SCpA, I-34012 Trieste, Italy (literal)
Titolo
  • In-situ X-ray photoelectron spectroscopy study of catalyst-support interactions and growth of carbon nanotube forests (literal)
Abstract
  • We study catalyst support interactions during chemical vapor deposition of carbon nanotubes by in situ X-ray photoelectron spectroscopy over a wide range of pressures. We observe Fe 2+ and 3+ interface states for metallic Fe on Al2O3 in the absence of measurable Al reduction. This support interaction is much stronger than that on SiO2, and it restricts Fe surface mobility. The resulting much narrower Fe catalyst particle size distribution on Al2O3 leads to a higher carbon nanotube nucleation density and a vertical nanotube alignment due to proximity effects. We record the growth kinetics of carbon nanotube forests by optical imaging to understand effects that contribute to growth termination. (literal)
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