Temperature dependence of de Gennes narrowing and transport properties of liquid rubidium: Experimental and simulation results (Articolo in rivista)

Type
Label
  • Temperature dependence of de Gennes narrowing and transport properties of liquid rubidium: Experimental and simulation results (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Alternative label
  • Bertolini D., F. Demmel, and A. Tani (2007)
    Temperature dependence of de Gennes narrowing and transport properties of liquid rubidium: Experimental and simulation results
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Bertolini D., F. Demmel, and A. Tani (literal)
Pagina inizio
  • 094204 (literal)
Pagina fine
  • 094212 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 71 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • D. Bertolini Istituto per i Processi Chimico-Fisici del Consiglio Nazionale delle Ricerche, Via Moruzzi 1, I-56124 Pisa, Italy F. Demmel ISIS Facility, Rutherford Appleton Laboratory, Chilton OX11 0QX, United Kingdom A. Tani Dipartimento di Chimica e Chimica Industriale, Universita' di Pisa, Via Risorgimento 35, I-56126 Pisa, Italy (literal)
Titolo
  • Temperature dependence of de Gennes narrowing and transport properties of liquid rubidium: Experimental and simulation results (literal)
Abstract
  • Recent neutron scattering results [F. Demmel et al., Phys. Rev. B 73, 104207 (2006)] on the temperature dependence of de Gennes narrowing in liquid rubidium have stimulated a molecular dynamics (MD) study in the same temperature and density range. At the k value of the first peak of S(k), the MD results agree very well with experimental data of S-tilde(kmax,omega=0), F(kmax,t=0), and longitudinal viscosity etaL(kmax,omega=0). Other transport properties, such as self-diffusion and shear viscosity, are also accurately reproduced. At k=0, on the other hand, the MD results significantly underestimate the experimental values of bulk viscosity and thermal conductivity. For the latter, this is a well known deficiency of models which do not explicitly take into account the electronic contribution to thermal exchanges. However, the large difference between MD and macroscopic experimental data for bulk viscosity casts some doubts on its indirect calculation from sound absorption data. This contradictory result, which presumably extends to all alkali metals, is discussed in the light of various theoretical models. (literal)
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