Uncharged water-soluble porphyrin tweezers as supramolecular sensor for alpha-amino acids (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Uncharged water-soluble porphyrin tweezers as supramolecular sensor for alpha-amino acids (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1088/0957-4484/18/37/375503 (literal)

Alternative label

• V. Villari; P. Mineo; N. Micali; N. Angelini; D. Vitalini; E. Scamporrino (2007)
  Uncharged water-soluble porphyrin tweezers as supramolecular sensor for alpha-amino acids
  in Nanotechnology (Bristol. Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• V. Villari; P. Mineo; N. Micali; N. Angelini; D. Vitalini; E. Scamporrino (literal)

Pagina inizio

• 375503 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 18 (literal)

Rivista

• Nanotechnology (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 13 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• CNR-Istituto per i Processi Chimico-Fisici, Via La Farina 237, I-98123 Messina, Italy Dipartimento di Scienze Chimiche, Universit`a di Catania, Viale Andrea Doria 6,I-95125 Catania, Italy CNR-Istituto di Chimica e Tecnologia dei Polimeri, Viale Andrea Doria 6, I-95125 Catania, Italy (literal)

Titolo

• Uncharged water-soluble porphyrin tweezers as supramolecular sensor for alpha-amino acids (literal)

Abstract

• The binding between uncharged cobalt porphyrin tweezers and L-amino acids in aqueous solutions is studied by means of UV–vis and circular dichroism spectroscopy. By varying the length of the aliphatic bridge between the two porphyrin units, the number of cobalt ions in the porphyrin cores and the pH of the solution, the chirality induction phenomenon has been investigated. The binding of the amino acid to the porphyrin seems to occur via a coordination mechanism between the metal and the nitrogen of the amino group; the steric, hydrophobic and pi–pi interactions operate to stabilize the complexes. The chirogenesis displays an opposite behaviour in the presence of aromatic guests with respect to the non-aromatic ones. Moreover, the UV–vis and the induced circular dichroism spectral changes suggest that the amino acid arrangement in the tweezers is determined by many factors, so that, unlike in organic solvent, the porphyrin tweezers in aqueous solution allow for two different arrangements of the same aromatic amino acid. The experimental findings indicate that the porphyrins tweezers reported in the paper are promising in opening perspectives toward their application as a selective molecular sensor in aqueous solutions directly. (literal)

Prodotto di

• Institute of structure of matter (ISM) (Istituto)
• Istituto di chimica e tecnologia dei polimeri (ICTP) (Istituto)
• Sistemi macromolecolari, polimeri e fluidi complessi (MD.P01.014.001) (Modulo)
• Istituto per i processi chimico-fisici (IPCF) (Istituto)

Autore CNR

• DANIELE VITALINI (Unità di personale interno)
• VALENTINA VILLARI (Persona)
• NORBERTO LIBORIO MICALI (Persona)
• NICOLA ANGELINI (Persona)

Incoming links:

Prodotto

• Istituto per i processi chimico-fisici (IPCF) (Istituto)
• Institute of structure of matter (ISM) (Istituto)
• Istituto di chimica e tecnologia dei polimeri (ICTP) (Istituto)
• Sistemi macromolecolari, polimeri e fluidi complessi (MD.P01.014.001) (Modulo)

Autore CNR di

• DANIELE VITALINI (Unità di personale interno)
• NICOLA ANGELINI (Persona)
• NORBERTO LIBORIO MICALI (Persona)
• VALENTINA VILLARI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Nanotechnology (Rivista)