New Experimental and Theoretical Results for Argon Broadening and Shift of HCO+ Rotational Lines (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• New Experimental and Theoretical Results for Argon Broadening and Shift of HCO+ Rotational Lines (Articolo in rivista) (literal)

Anno

• 2006-01-01T00:00:00+01:00 (literal)

Alternative label

• G. Buffa (1), L. Dore (2), F. Tinti (2) and M. Mewuly (3) (2006)
  New Experimental and Theoretical Results for Argon Broadening and Shift of HCO+ Rotational Lines
  in ChemPhysChem (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• G. Buffa (1), L. Dore (2), F. Tinti (2) and M. Mewuly (3) (literal)

Pagina inizio

• 1764 (literal)

Pagina fine

• 1769 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 7 (literal)

Rivista

• ChemPhysChem (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1 IPCF - CNR 2 Dipartimento di Chimica dell'Università di Bologna 3 Dipartimento di Chimica dell'Università di Basilea (literal)

Titolo

• New Experimental and Theoretical Results for Argon Broadening and Shift of HCO+ Rotational Lines (literal)

Abstract

• An experimental and theoretical study of the pressure broadening and the pressure shift of three HCO+ rotational lines (j=4-3, 5-4 and 6-5) perturbed by collisions with Ar is presented. The measurements are carried out at 77 K and are compared to close-coupling calculations performed on an accurate potential energy surface for the Ar-HCO+ interaction extending from small to very large separations between the ion and the perturber. For the pressure broadening, agreement between experiment and theory is satisfactory for both close-coupling and semiclassical calculations. For the pressure shift, however, close-coupling calculations are superior. The results agree with experiment in sign and order of magnitude, while semiclassical calculations are inaccurate for the shift of the presently studied lines because they neglect the contribution of strong collisions. (literal)

Prodotto di

• Institute for chemical and physical processes (IPCF) (Istituto)
• Struttura e dinamica in sistemi autoorganizzati e cooperativi (MD.P01.012.001) (Modulo)

Autore CNR

• GIOVANNI BUFFA (Unità di personale interno)

Incoming links:

Prodotto

• Institute for chemical and physical processes (IPCF) (Istituto)
• Struttura e dinamica in sistemi autoorganizzati e cooperativi (MD.P01.012.001) (Modulo)

Autore CNR di

• GIOVANNI BUFFA (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• ChemPhysChem (Rivista)