Intramolecular versus intermolecular C-H activation reaction in the thermolysis of [Ru(Me)Cp*(PMe2Ph)2] (Cp*=n5-C5Me5): formation and crystallographic characterization of [Ru(Ph)Cp*(PMe2Ph)2] (Articolo in rivista)

Type
Label
  • Intramolecular versus intermolecular C-H activation reaction in the thermolysis of [Ru(Me)Cp*(PMe2Ph)2] (Cp*=n5-C5Me5): formation and crystallographic characterization of [Ru(Ph)Cp*(PMe2Ph)2] (Articolo in rivista) (literal)
Anno
  • 2005-01-01T00:00:00+01:00 (literal)
Alternative label
  • P. Diversi, M. Fuligni, F. Marchetti, S. Matteoni, C. Pinzino (2005)
    Intramolecular versus intermolecular C-H activation reaction in the thermolysis of [Ru(Me)Cp*(PMe2Ph)2] (Cp*=n5-C5Me5): formation and crystallographic characterization of [Ru(Ph)Cp*(PMe2Ph)2]
    in Journal of organometallic chemistry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • P. Diversi, M. Fuligni, F. Marchetti, S. Matteoni, C. Pinzino (literal)
Pagina inizio
  • 605 (literal)
Pagina fine
  • 612 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 690 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Dipartimento di Chimica e Chimica Industriale, dell'Universita` di Pisa, Via Risorgimento 35, 56126 Pisa, Italy Istituto per i Processi Chimico-Fisici del C.N.R., Area della Ricerca di Pisa, Via G. Moruzzi 1, 56124 Pisa, Italy (literal)
Titolo
  • Intramolecular versus intermolecular C-H activation reaction in the thermolysis of [Ru(Me)Cp*(PMe2Ph)2] (Cp*=n5-C5Me5): formation and crystallographic characterization of [Ru(Ph)Cp*(PMe2Ph)2] (literal)
Abstract
  • Thermolysis of the ruthenium complex [Ru(Me)Cp*(PMe2Ph)2] (1) (Cp* = g5-C5Me5) in benzene gives methane and [Ru(Ph)Cp*(PMe2Ph)2] (2), which is converted slowly to [Ru(C6H4PMe2)Cp*(PMe2Ph)] (3) through the loss of benzene. 2 was structurally characterised by single-crystal X-ray diffraction experiments. DFT calculations were performed in order to understand the behaviour of the ruthenium complex 1 towards inter- or intra-molecular C–H bond activation reactions. (literal)
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