http://www.cnr.it/ontology/cnr/individuo/prodotto/ID39493
Intramolecular versus intermolecular C-H activation reaction in the thermolysis of [Ru(Me)Cp*(PMe2Ph)2] (Cp*=n5-C5Me5): formation and crystallographic characterization of [Ru(Ph)Cp*(PMe2Ph)2] (Articolo in rivista)
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- Label
- Intramolecular versus intermolecular C-H activation reaction in the thermolysis of [Ru(Me)Cp*(PMe2Ph)2] (Cp*=n5-C5Me5): formation and crystallographic characterization of [Ru(Ph)Cp*(PMe2Ph)2] (Articolo in rivista) (literal)
- Anno
- 2005-01-01T00:00:00+01:00 (literal)
- Alternative label
P. Diversi, M. Fuligni, F. Marchetti, S. Matteoni, C. Pinzino (2005)
Intramolecular versus intermolecular C-H activation reaction in the thermolysis of [Ru(Me)Cp*(PMe2Ph)2] (Cp*=n5-C5Me5): formation and crystallographic characterization of [Ru(Ph)Cp*(PMe2Ph)2]
in Journal of organometallic chemistry (Print)
(literal)
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- P. Diversi, M. Fuligni, F. Marchetti, S. Matteoni, C. Pinzino (literal)
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- ISI Web of Science (WOS) (literal)
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- Dipartimento di Chimica e Chimica Industriale, dell'Universita` di Pisa, Via Risorgimento 35, 56126 Pisa, Italy
Istituto per i Processi Chimico-Fisici del C.N.R., Area della Ricerca di Pisa, Via G. Moruzzi 1, 56124 Pisa, Italy (literal)
- Titolo
- Intramolecular versus intermolecular C-H activation reaction in the thermolysis of [Ru(Me)Cp*(PMe2Ph)2] (Cp*=n5-C5Me5): formation and crystallographic characterization of [Ru(Ph)Cp*(PMe2Ph)2] (literal)
- Abstract
- Thermolysis of the ruthenium complex [Ru(Me)Cp*(PMe2Ph)2] (1) (Cp* = g5-C5Me5) in benzene gives methane and
[Ru(Ph)Cp*(PMe2Ph)2] (2), which is converted slowly to [Ru(C6H4PMe2)Cp*(PMe2Ph)] (3) through the loss of benzene. 2 was structurally
characterised by single-crystal X-ray diffraction experiments. DFT calculations were performed in order to understand the
behaviour of the ruthenium complex 1 towards inter- or intra-molecular CH bond activation reactions. (literal)
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