http://www.cnr.it/ontology/cnr/individuo/prodotto/ID39492
Reactivity of bis(g6-arene) derivatives of titanium, vanadium and niobium with fulvenes bearing electron-withdrawing substituents (Articolo in rivista)
- Type
- Label
- Reactivity of bis(g6-arene) derivatives of titanium, vanadium and niobium with fulvenes bearing electron-withdrawing substituents (Articolo in rivista) (literal)
- Anno
- 2005-01-01T00:00:00+01:00 (literal)
- Alternative label
Lucia Calucci, Ulli Englert, Guido Pampaloni, Calogero Pinzino, Manuel Volpe (2005)
Reactivity of bis(g6-arene) derivatives of titanium, vanadium and niobium with fulvenes bearing electron-withdrawing substituents
in Journal of organometallic chemistry (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Lucia Calucci, Ulli Englert, Guido Pampaloni, Calogero Pinzino, Manuel Volpe (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Istituto per i Processi Chimico-Fisici, CNR, Area della Ricerca, Via G. Moruzzi 1, I-56124 Pisa, Italy
Institut fur Anorganische Chemie der RWTH Aachen, Landoltweg 1, D-52074 Aachen, Germany
Dipartimento di Chimica e Chimica Industriale, Universita` di Pisa, Via Risorgimento 35, I-56126 Pisa, Italy (literal)
- Titolo
- Reactivity of bis(g6-arene) derivatives of titanium, vanadium and niobium with fulvenes bearing electron-withdrawing substituents (literal)
- Abstract
- The reaction of M(g6-arene)2 (M = Ti, arene = MeC6H5; M = V, Nb, arene = 1,3,5-Me3C6H3) with \"pentacarbomethoxycyclopentadiene\"
(pcmcpH), 1-benzoyl-6-hydroxy-6-phenyl fulvene (dbcpH), and 1-benzoyl-3-nitro-6-hydroxy-6-phenyl fulvene
(dbncpH) proceeds with evolution of dihydrogen and oxidation of the metal to coordination compounds containing O,O0-coordinated
cyclopentadienyl anions, i.e., [pcmcp]-, [dbcp]-, and [dbncp]-, respectively. Complexes of general formula M(O,O0-anion)3,
where the metal is in the +III oxidation state, have been isolated for titanium and niobium. In the case of vanadium, different compounds
have been obtained depending on the fulvene and the reaction conditions. In particular, solvated derivatives of vanadium(II)
of general formula V(O,O0-anion)2(THF)2 have been prepared in THF whereas V(O,O0-anion)2 complexes have been isolated in
toluene even in the presence of excess fulvene. (literal)
- Prodotto di
- Autore CNR
Incoming links:
- Prodotto
- Autore CNR di
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi