Transition Metal Derivatives of 1,10-Phenanthroline-5,6-dione: Controlled Growth of Coordination Polynuclear Derivatives (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Transition Metal Derivatives of 1,10-Phenanthroline-5,6-dione: Controlled Growth of Coordination Polynuclear Derivatives (Articolo in rivista) (literal)

Anno

• 2006-01-01T00:00:00+01:00 (literal)

Alternative label

• L. Calucci, G. Pampaloni, C. Pinzino, A. Prescimone (2006)
  Transition Metal Derivatives of 1,10-Phenanthroline-5,6-dione: Controlled Growth of Coordination Polynuclear Derivatives
  in Inorganica Chimica Acta (Testo stamp.)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• L. Calucci, G. Pampaloni, C. Pinzino, A. Prescimone (literal)

Pagina inizio

• 3911 (literal)

Pagina fine

• 3920 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 359 (literal)

Rivista

• Inorganica Chimica Acta (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto per i Processi Chimico-Fisici, CNR, Area della Ricerca, Via G. Moruzzi 1, I-56124 Pisa, Italy Universita` di Pisa, Dipartimento di Chimica e Chimica Industriale, Via Risorgimento 35, I-56126 Pisa, Italy (literal)

Titolo

• Transition Metal Derivatives of 1,10-Phenanthroline-5,6-dione: Controlled Growth of Coordination Polynuclear Derivatives (literal)

Abstract

• The synthesis and the characterization of several mono- and polymetallic derivatives of 1,10-phenanthroline-5,6,-dione (1) are presented. The reaction of 1 with M(CO)6 (M = Cr, Mo) gives compounds of general formula M(O,O0-C12H6N2O2)3, M=Cr (2), Mo (3).Compound 3 is also obtained starting from Mo(g6-CH3C6H5)2, whereas the reaction of Cr(g6-CH3C6H5)2 with 1 affords the ionic derivative [Cr(g6-CH3C6H5)2][C12H6N2O2] (4), which has been studied by EPR spectroscopy and DFT calculations.FeCl2(N,N0- C12H6N2O2)2 (6), is obtained by thermal decomposition of [Fe(N,N0-C12H6N2O2)3]Cl2 (5).Polymetallic compounds of general formula Cr[O,O0-C12H6N2O2-N,N0-MCl4]3,containing chromium and a Group 4 element M = Ti (7), Zr (8), Hf (9), are prepared from Cr(O,O0-C12H6N2O2)3 and the corresponding MCl4 or MCl4DME. Polynuclear derivatives of iron and chromium of formula [Fe(N,N0-C12H6N2O2-O,O0-CrCl2(THF)2)3][PF6]2 (10), and Cr[O,O0-C12H6N2O2-N,N0-FeCl2(THF)]3 (11), are obtained by the reaction of [Fe(N,N0-C12H6N2O2)3][PF6]2 with three equivalents of CrCl2(THF)2 and from Cr(O,O0-C12H6N2O2)3 and FeCl2(THF)1.5, respectively. Compound 11 reacts with 1 (3 equivalents in sym-C2H2Cl4 or 6 equivalents in ethanol) to give Cr[O,O0-C12H6N2O2-N,N0- FeCl2(N,N0-C12H6N2O2)]3 (12), and [Cr(O,O0-C12H6N2O2-N,N0-Fe(N,N0-C12H6N2O2)2)3]Cl6 (13), respectively. (literal)

Prodotto di

• Struttura e dinamica in sistemi autoorganizzati e cooperativi (MD.P01.012.001) (Modulo)
• Istituto per i processi chimico-fisici (IPCF) (Istituto)

Autore CNR

• CALOGERO PINZINO (Unità di personale interno)
• LUCIA CALUCCI (Persona)

Insieme di parole chiave

• Keywords of "Transition Metal Derivatives of 1,10-Phenanthroline-5,6-dione: Controlled Growth of Coordination Polynuclear Derivatives" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto per i processi chimico-fisici (IPCF) (Istituto)
• Struttura e dinamica in sistemi autoorganizzati e cooperativi (MD.P01.012.001) (Modulo)

Autore CNR di

• CALOGERO PINZINO (Unità di personale interno)
• LUCIA CALUCCI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganica Chimica Acta (Rivista)

Insieme di parole chiave di

• Keywords of "Transition Metal Derivatives of 1,10-Phenanthroline-5,6-dione: Controlled Growth of Coordination Polynuclear Derivatives" (Insieme di parole chiave)