Some New Results on the Fischer-Hafner Synthesis of Vanadium Arenes (Articolo in rivista)

Type
Label
  • Some New Results on the Fischer-Hafner Synthesis of Vanadium Arenes (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Alternative label
  • F. Marchetti, G. Pampaloni, C. Pinzino (2006)
    Some New Results on the Fischer-Hafner Synthesis of Vanadium Arenes
    in Journal of organometallic chemistry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • F. Marchetti, G. Pampaloni, C. Pinzino (literal)
Pagina inizio
  • 3458 (literal)
Pagina fine
  • 3463 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 691 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Universita` di Pisa, Dipartimento di Chimica e Chimica Industriale, Via Risorgimento 35, I-56126 Pisa, Italy Istituto per i Processi Chimico-Fisici, CNR, Area della Ricerca, Via G. Moruzzi 1, I-56124 Pisa, Italy (literal)
Titolo
  • Some New Results on the Fischer-Hafner Synthesis of Vanadium Arenes (literal)
Abstract
  • The biphasic liquid system formed in the Fisher–Hafner reduction of VCl3 in toluene contains the [V(g6-MeC6H5)2]+ cation which has been isolated in the solid state as the tetraphenylborato- (from aqueous solution) or as the [Al2Cl7]-, [Al4O2Cl10]2- and [catena- Al4O2Cl9]- salt (directly from the biphasic liquid system). The crystal structures of [V(h6-MeC6H5)2]2[Al4O2Cl10] (2), and [V(h6- MeC6H5)2][catena-Al4O2Cl9] (3), have been solved representing the first structural report of the [V(g6-MeC6H5)2]+ cation (compounds 2 and 3) and of the polymeric nonachlorodioxoaluminate anion [Al4O2Cl9]- (compound 3). (literal)
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