Optically induced circular and axial birefringences in achiral fluids: an ab initio study of the optical Faraday effect (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Optically induced circular and axial birefringences in achiral fluids: an ab initio study of the optical Faraday effect (Articolo in rivista) (literal)

Anno

• 2006-01-01T00:00:00+01:00 (literal)

Alternative label

• Baranowska, A.; Rizzo, A.; Coriani, S. (2006)
  Optically induced circular and axial birefringences in achiral fluids: an ab initio study of the optical Faraday effect
  in Molecular physics (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Baranowska, A.; Rizzo, A.; Coriani, S. (literal)

Pagina inizio

• 2173 (literal)

Pagina fine

• 2192 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 104 (literal)

Rivista

• Molecular physics (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto per i Processi Chimico-Fisici del Consiglio Nazionale delle Ricerche, Area della Ricerca, via G. Moruzzi 1, I-56124 Pisa, Italy Department of Quantum Chemistry, Institute of Chemistry, Nicolaus Copernicus University, 7, Gagarin St., PL-87 100 Torun, Poland Dipartimento di Scienze Chimiche, Università degli studi di Trieste, via L. Giorgieri 1, I-34127 Trieste, Italy (literal)

Titolo

• Optically induced circular and axial birefringences in achiral fluids: an ab initio study of the optical Faraday effect (literal)

Abstract

• A computational analysis of the effects (intensity-dependent change in the refractive index and the optical Faraday effect, OFE) induced in an achiral fluid by circularly polarized, linearly polarized or unpolarized light is presented. The connection between the molecular parameters appearing in the expression of the observable, as derived by Woz´ niak in the 1990s, and the appropriate linear and cubic frequency dependent response functions is made for the general case of both chiral and non-chiral fluid. The parameters which are non-vanishing in the case of achiral systems are then computed employing a coupled cluster singles and doubles wave function model and a wide choice of correlation consistent basis sets, for a set of reference systems, including a rare gas (neon), a non-dipolar (N2) and a dipolar (CO) molecule. Contributions due to magnetic and quadrupolar interactions between the fields and the gases are neglected, since they are in principle of much less importance than the purely electric dipolar interactions. Nevertheless a rough estimate of their size is given. The aim of the study is to assess the detectability of OFE. To this end, the ab initio results are compared with those obtained in this work for the closely related optical Kerr effect (OKE) and with those yielded by the classical Faraday effect. (literal)

Prodotto di

• Istituto per i processi chimico-fisici (IPCF) (Istituto)
• Modellizzazione di proprietà e reattività di molecole biologiche e biomimetiche (MD.P01.013.001) (Modulo)

Autore CNR

• ANGELIKA BARANOWSKA (Unità di personale esterno)
• ANTONIO RIZZO (Persona)

Incoming links:

Prodotto

• Istituto per i processi chimico-fisici (IPCF) (Istituto)
• Modellizzazione di proprietà e reattività di molecole biologiche e biomimetiche (MD.P01.013.001) (Modulo)

Autore CNR di

• ANTONIO RIZZO (Persona)
• ANGELIKA BARANOWSKA (Unità di personale esterno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Molecular physics (Rivista)