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Phonon-like dynamics in glasses: Coupling between damping and fragility (Articolo in rivista)
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- Phonon-like dynamics in glasses: Coupling between damping and fragility (Articolo in rivista) (literal)
- Anno
- 2006-01-01T00:00:00+01:00 (literal)
- Alternative label
Bove, LE; Petrillo, C; Fontana, A; Ivanov, A; Dreyfus, C; Sokolov, AP (2006)
Phonon-like dynamics in glasses: Coupling between damping and fragility
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Bove, LE; Petrillo, C; Fontana, A; Ivanov, A; Dreyfus, C; Sokolov, AP (literal)
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- ISI Web of Science (WOS) (literal)
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- Univ Roma La Sapienza, INFM, CRS, SOFT, I-00185 Rome, Italy; Univ Paris 06, IMPMC, F-75015 Paris, France; Univ Perugia, Dipartimento Fis, I-06123 Perugia, Italy; Univ Trent, Dipartimento Fis, I-38050 Trento, Italy; Inst Max Von Laue Paul Langevin, F-38100 Grenoble, France; Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA (literal)
- Titolo
- Phonon-like dynamics in glasses: Coupling between damping and fragility (literal)
- Abstract
- The high-frequency dynamics of two strong glasses, v-GeO2 and v-ZnCl2, were studied by means of inelastic neutron scattering experiments carried out with three triple-axis spectrometers in order to selectively access either a wide kinematic region or a high-energy resolution. The experimental spectra show well-defined dispersive acoustic excitations coexisting with non-dispersive waves. A thorough analysis of the inelastic line shape of longitudinal acoustic excitations provides estimates of the damping factors, which can be compared to the results of several earlier inelastic X-ray estimates for a wide class of inorganic glasses. A striking relation is observed between the microscopic damping of phonon-like modes in these glasses well below T-g and the fragility of the supercooled liquids approaching the glass transition, thus suggesting new means of investigation of the glass transition phenomenology. (c) 2006 Elsevier B.V. All rights reserved. (literal)
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