Metal Oxide Nanocrystals from the Injection of Metal Oxide Sols in a Coordinating Environment: Principles, Applicability, and Investigation of the Synthesis Variables in the Case Study of CeO2 and SnO2 (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Metal Oxide Nanocrystals from the Injection of Metal Oxide Sols in a Coordinating Environment: Principles, Applicability, and Investigation of the Synthesis Variables in the Case Study of CeO2 and SnO2 (Articolo in rivista) (literal)

Anno

• 2009-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/cm803282k (literal)

Alternative label

• Epifani M, Pellicer E, Arbiol J, Morante JR (2009)
  Metal Oxide Nanocrystals from the Injection of Metal Oxide Sols in a Coordinating Environment: Principles, Applicability, and Investigation of the Synthesis Variables in the Case Study of CeO2 and SnO2
  in Chemistry of materials
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Epifani M, Pellicer E, Arbiol J, Morante JR (literal)

Pagina inizio

• 862 (literal)

Pagina fine

• 870 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 21 (literal)

Rivista

• Chemistry of materials (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 5 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1. CNR, IMM, I-73100 Lecce, Italy 2. Univ Barcelona, EME XaRMAE IN2UB, Dept Elect, E-08028 Barcelona, CAT Spain 3. Univ Barcelona, MIND IN2UB, Dept Elect, E-08028 Barcelona, CAT Spain 4. Univ Barcelona, TEM MAT, Serv Cientificotecn, E-08028 Barcelona, CAT Spain 5. IREC, Barcelona 08019, Spain (literal)

Titolo

• Metal Oxide Nanocrystals from the Injection of Metal Oxide Sols in a Coordinating Environment: Principles, Applicability, and Investigation of the Synthesis Variables in the Case Study of CeO2 and SnO2 (literal)

Abstract

• Metal oxide sols (ZnO, SnO2, TiO2, ZrO2, Fe2O3, NiO, Ga2O3, MnO2, In2O3, CeO2) were prepared by hydrolysis of chloro-alkoxo or acetylacetonato complexes, preventing precipitation. The sols were injected in a solution of tetradecene and an aliphatic amine at 160 degrees C and heated at the resulting temperature for 3 h, resulting in the formation of metal oxide nanoparticles. The crystallization degree of the resulting nanoparticles depended on the particular system, and nanocrystals were obtained for ZnO, SnO2, Fe2O3, Ga2O3, In2O3, CeO2 systems. The chemical features of the process were investigated on SnO2 and CeO2 as case systems, by X-ray diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy, and nuclear magnetic resonance. The initial hypothesis that the amine present in the injection solution may act at the same time as a catalyst of the inorganic condensation reactions and as a growth stopper by bonding to the surface metal atoms of the nanoparticles, was thoroughly investigated and it resulted that the alkylamine structure and the processing of the starting Sol can influence the nanocrystal formation pathway. In particular, bulkier amines favor the formation of smaller nanocrystals, whereas favoring the condensation reactions in the starting sols results in larger nanocrystals. (literal)

Prodotto di

• Institute for microelectronics and microsystems (IMM) (Istituto)
• Sensori e Microsistemi Intelligenti per la Sicurezza e la Qualità della vita nei settori Agroalimentare, Trasporti ed \"Ambient Assisted Living\" (MD.P05.010.001) (Modulo)

Autore CNR

• MAURO SALVATORE EPIFANI (Persona)

Incoming links:

Prodotto

• Institute for microelectronics and microsystems (IMM) (Istituto)
• Sensori e Microsistemi Intelligenti per la Sicurezza e la Qualità della vita nei settori Agroalimentare, Trasporti ed \"Ambient Assisted Living\" (MD.P05.010.001) (Modulo)

Autore CNR di

• MAURO SALVATORE EPIFANI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Chemistry of materials (Rivista)