Synthesis of tailored phthalocyanines and their application as spin coated films in volatile organic compound detection (Articolo in rivista)

Type
Label
  • Synthesis of tailored phthalocyanines and their application as spin coated films in volatile organic compound detection (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Alternative label
  • Spadavecchia J., Ciccarella G., Buccolieri A., Vasapollo G., Rella R. (2003)
    Synthesis of tailored phthalocyanines and their application as spin coated films in volatile organic compound detection
    in Journal of porphyrins and phthalocyanines
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Spadavecchia J., Ciccarella G., Buccolieri A., Vasapollo G., Rella R. (literal)
Pagina inizio
  • 572 (literal)
Pagina fine
  • 578 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 7 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Univ Lecce, Dipartimento Ingn Innovaz, I-73100 Lecce, Italy; CNR, IMM, Sez Lecce, I-73100 Lecce, Italy (literal)
Titolo
  • Synthesis of tailored phthalocyanines and their application as spin coated films in volatile organic compound detection (literal)
Abstract
  • 29H,31H-(2,4-di-t-amylphenoxy)phthalocyanine, Zn(II) tetra-4-(2,4-di-t-amylphenoxy)phthalocyanine and Zn(II) tris-(2,4-di-t-amylphenoxy)-[4-(4-mercapto-phenylimino-methyl)-phenoxy]phthalocyanine were synthesized and their molecular structures were confirmed by LC-MS, H-1 NMR, FT-IR and UV-vis spectra. Spin coated layers of these phthalocyanines have been used as optochemically interactive materials for volatile organic compounds detection in the UV-vis spectral range. The results show a good sensitivity and selectivity depending on both the metal and the peripheral substituents. Optical sensitivity towards tert-butylamine, diethylamine, dibutylamine, 2-butanone and acetic acid has been monitored. (literal)
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