http://www.cnr.it/ontology/cnr/individuo/prodotto/ID36308
Solid state dehalogenation of PCBs in contaminated soil using NaBH4 (Articolo in rivista)
- Type
- Label
- Solid state dehalogenation of PCBs in contaminated soil using NaBH4 (Articolo in rivista) (literal)
- Anno
- 2003-01-01T00:00:00+01:00 (literal)
- Alternative label
Aresta M., Caramuscio P., De Stefano L., Pastore T. (2003)
Solid state dehalogenation of PCBs in contaminated soil using NaBH4
in Waste management (Elmsford)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Aresta M., Caramuscio P., De Stefano L., Pastore T. (literal)
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- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Univ Bari, Dept Chem, METEA Res Ctr, I-70126 Bari, Italy; Litoranea Salentina Brindisi Casalabate, Local Cerano, Enel Prod Ric, I-72020 Tuturano, Brindisi, Italy; CNR, IMM, I-80124 Naples, Italy; METEA Res Ctr, Unit Bari, INCA, I-70126 Bari, Italy (literal)
- Titolo
- Solid state dehalogenation of PCBs in contaminated soil using NaBH4 (literal)
- Abstract
- In this work we present the results of an experimental study on the abatement of polychlorinated biphenyl (PCBs) in contaminated soil using a high energy milling technique, that promotes a reaction only by impact between milling bodies. A sample of soil from a controlled landfill was treated with powdered NaBH4 using two different hydride/soil ratios (5 and 2.5% w/w). The efficiency of the dehalogenation/hydrogenation reaction was studied as a function of the milling time (3.5 up to 30 h). After each run, the total PCBs content and the production of inorganic chloride were measured. The complete abatement was obtained with a starting PCBs concentration of about 2600 mg/kg. The residual PCBs concentration resulted to be <0.2 mg/kg. The final products of the treatment were biphenyl and NaCl. Other toxic or hazardous organic by-products were not generated. Boron was found as boric acid. (literal)
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- Autore CNR
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