Wet absorption of a Eu(III)-complex on Carbon Nanotubes Sidewwalls (Articolo in rivista)

Type
Label
  • Wet absorption of a Eu(III)-complex on Carbon Nanotubes Sidewwalls (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Alternative label
  • Accorsi G, Armaroli N, Parisini A, Meneghetti M, Marea R, Prato M, Bonifazi D (2007)
    Wet absorption of a Eu(III)-complex on Carbon Nanotubes Sidewwalls
    in Advanced functional materials (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Accorsi G, Armaroli N, Parisini A, Meneghetti M, Marea R, Prato M, Bonifazi D (literal)
Pagina inizio
  • 2975 (literal)
Pagina fine
  • 2982 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 17 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR, Ist Sintesi Organ & Fororeattivit, Mol Photosci Grp, Bologna, Italy; CNR-IMM, Bologna, Italy; Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy; Univ Trieste, Dipartimento Sci Farmaceut, I-34127 Trieste, Italy; Univ Trieste, INSTM UdR Trieste, I-34127 Trieste, Italy (literal)
Titolo
  • Wet absorption of a Eu(III)-complex on Carbon Nanotubes Sidewwalls (literal)
Abstract
  • A Eu-III complex, tris-dibenzoylmethane mono-1,10-phenanthroline-europium(III) [Eu(DBM)(3)(Phen)], can be easily adsorbed If in situ via hydrophobic interactions to single-walled carbon nanotube (SWNT) surfaces from a methanol solution. The Eu-III containing material has been comprehensively characterized via thermogravimetric analysis (TGA), UV-vis-NIR absorption and luminescence spectroscopy, Raman spectroscopy, atomic force microscopy (AFM), high-resolution transmission electron microscopy (HR-TEM)), Z-contrast scanning transmission electron microscopy (STEM) imaging, and energy dispersive X-ray spectroscopy (EDS). The photophysical investigations revealed that the presence of a SWNT framework does not affect the lanthanide-centered luminescence stemming from the characteristic electronic transitions within the 4f shell of the Eu-III, ions. Such straightforward synthetic route leads to the preparation of luminescent SWNTs without significantly affecting the electronic and structural properties of the carbon framework, opening new possibilities of designing new classes of CNTs for biomedical applications. (literal)
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