http://www.cnr.it/ontology/cnr/individuo/prodotto/ID35996
Precursors for the combustion synthesis of metal oxides from the sol-gel processing of metal complexes (Articolo in rivista)
- Type
- Label
- Precursors for the combustion synthesis of metal oxides from the sol-gel processing of metal complexes (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Alternative label
Epifani M, Melissano E, Pace G, Schioppa M (2007)
Precursors for the combustion synthesis of metal oxides from the sol-gel processing of metal complexes
in Journal of the European Ceramic Society
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Epifani M, Melissano E, Pace G, Schioppa M (literal)
- Pagina inizio
- Pagina fine
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- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- CNR, IMM, I-73100 Lecce, Italy;
UTS MAT, ENEA CR Brindisi, I-72100 Brindisi, Italy (literal)
- Titolo
- Precursors for the combustion synthesis of metal oxides from the sol-gel processing of metal complexes (literal)
- Abstract
- Sol-gel processing of methanol solutions of Cu(II) acetylacetonates was used for obtaining controlled polymerization of the complex molecules. The resulting sols were evaporated and the resulting precipitate was heated until a self-sustaining combustion reaction took place. The simultaneous presence of nitrate ions and the acetylacetonato ligands resulted in a sharp combustion process, characterized by low activation temperature and intense exothermic feature. The same processing was applied to other metals and other ligands, showing that the sol-gel processing of transition metal complexes can be a simple, convenient, flexible generalization of the citrate-nitrate method for preparing precursors for the combustion synthesis of oxide powders. Moreover, the controlled sol-gel processing of the metal complex can be used as a tool for controlling the precursor structure and. hence, the morphology of the final product. (literal)
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- Autore CNR
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