Precursors for the combustion synthesis of metal oxides from the sol-gel processing of metal complexes (Articolo in rivista)

Type
Label
  • Precursors for the combustion synthesis of metal oxides from the sol-gel processing of metal complexes (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Alternative label
  • Epifani M, Melissano E, Pace G, Schioppa M (2007)
    Precursors for the combustion synthesis of metal oxides from the sol-gel processing of metal complexes
    in Journal of the European Ceramic Society
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Epifani M, Melissano E, Pace G, Schioppa M (literal)
Pagina inizio
  • 115 (literal)
Pagina fine
  • 123 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 27 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR, IMM, I-73100 Lecce, Italy; UTS MAT, ENEA CR Brindisi, I-72100 Brindisi, Italy (literal)
Titolo
  • Precursors for the combustion synthesis of metal oxides from the sol-gel processing of metal complexes (literal)
Abstract
  • Sol-gel processing of methanol solutions of Cu(II) acetylacetonates was used for obtaining controlled polymerization of the complex molecules. The resulting sols were evaporated and the resulting precipitate was heated until a self-sustaining combustion reaction took place. The simultaneous presence of nitrate ions and the acetylacetonato ligands resulted in a sharp combustion process, characterized by low activation temperature and intense exothermic feature. The same processing was applied to other metals and other ligands, showing that the sol-gel processing of transition metal complexes can be a simple, convenient, flexible generalization of the citrate-nitrate method for preparing precursors for the combustion synthesis of oxide powders. Moreover, the controlled sol-gel processing of the metal complex can be used as a tool for controlling the precursor structure and. hence, the morphology of the final product. (literal)
Prodotto di
Autore CNR

Incoming links:


Autore CNR di
Prodotto
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
data.CNR.it