The early oxynitridation stages of hydrogen-terminated (100) silicon after exposure to N-2 : N2O. III. Initial conditions (Articolo in rivista)

Type
Label
  • The early oxynitridation stages of hydrogen-terminated (100) silicon after exposure to N-2 : N2O. III. Initial conditions (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1007/s00339-002-1997-0 (literal)
Alternative label
  • Cerofolini G.F., Galati C., Lorenti S., Renna L., Viscuso O., Bongiorno C., Raineri V., Spinella C., Condorelli G.G., Fragala I.L., Terrasi A. (2003)
    The early oxynitridation stages of hydrogen-terminated (100) silicon after exposure to N-2 : N2O. III. Initial conditions
    in Applied physics. A, Materials science & processing (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Cerofolini G.F., Galati C., Lorenti S., Renna L., Viscuso O., Bongiorno C., Raineri V., Spinella C., Condorelli G.G., Fragala I.L., Terrasi A. (literal)
Pagina inizio
  • 403 (literal)
Pagina fine
  • 409 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 77 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR, Inst Microelect & Microsyst, I-95121 Catania, CT, Italy; Univ Catania, Dept Chem, I-95121 Catania, CT, Italy; Univ Catania, INFM, I-95121 Catania, CT, Italy; Univ Catania, Dept Phys, I-95121 Catania, CT, Italy; STMicroelectronics, I-20041 Agrate Brianza, MI, Italy (literal)
Titolo
  • The early oxynitridation stages of hydrogen-terminated (100) silicon after exposure to N-2 : N2O. III. Initial conditions (literal)
Abstract
  • The structure and thermal stability in N-2 of hydrogen-terminated (100) silicon has been studied by X-ray photoemission spectroscopy, transmission electron microscopy, atomic force microscopy, thermal programmed desorption, and reflection high energy electron diffraction. Device-quality surfaces were prepared in an open-chamber reactor by exposing single crystalline, (100) oriented silicon to H-2 at high temperature (850 degreesC or 1100 degreesC) for durations on the order of 10(2) s. The observed stability with respect to N-2 at 850 degreesC is inconsistent with the reported desorption kinetics and may be accounted for in terms of either physico-chemical properties of the system (e.g., the presence of a buried layer of H-2 or of hydrogen-decorated vacancies whose out-diffusion restores the hydrogen terminations on the surface) or the reactor (persistence of hydrogen in the atmosphere even after switching it off). The nitridation by N-2 of hydrogen-terminated silicon is less efficient (per unit exposure) than that by N2O by 4 orders of magnitude. (literal)
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