Sorption kinetics and chemical forms of Cd(II) sorbed by thiol-functionalized 2 : 1 clay minerals (Articolo in rivista)

Type
Label
  • Sorption kinetics and chemical forms of Cd(II) sorbed by thiol-functionalized 2 : 1 clay minerals (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.jhazmat.2006.08.069 (literal)
Alternative label
  • Malferrari D; Brigatti M F; Laurora A; Pini S; Medici L (2007)
    Sorption kinetics and chemical forms of Cd(II) sorbed by thiol-functionalized 2 : 1 clay minerals
    in Journal of hazardous materials (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Malferrari D; Brigatti M F; Laurora A; Pini S; Medici L (literal)
Pagina inizio
  • 73 (literal)
Pagina fine
  • 81 (literal)
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  • 143 (literal)
Rivista
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  • 9 (literal)
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  • 1-2 (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
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  • (1) Dipartimento di Scienze della Terra, Universit`a di Modena e Reggio Emilia, Largo S. Eufemia 19, I-41100 Modena, Italy (2) IMAA-CNR, Area della Ricerca di Potenza, C. da S. Loja, I-85050 Tito Scalo, PZ, Italy (literal)
Titolo
  • Sorption kinetics and chemical forms of Cd(II) sorbed by thiol-functionalized 2 : 1 clay minerals (literal)
Abstract
  • The interaction between Cd(II) in aqueous solution and two 2:1 expandable clay minerals (i.e., montmorillonite and vermiculite), showing different layer charge, was addressed via batch sorption experiments on powdered clay minerals both untreated and amino acid (cysteine) treated. Reaction products were characterized via X-ray powder diffraction (XRDP), chemical analysis (elemental analysis and atomic absorption spectrophotometry), thermal analysis combined with evolved gasses mass spectrometry (TGA-MSEGA) and synchrotron-based X-ray absorption spectroscopy via extended X-ray absorption fine structure (EXAFS) characterization. Sorption isotherms for Cd(II) in presence of different substrates, shows that Cd(II) uptake depends both on Cd(II) starting concentration and the nature of the substrate. Thermal decomposition of Cd-cysteine treated clay minerals evidences the evolution of H2O, H2S, NO2, SO2, and N2O3. These results are well consistent with XRDP data collected both at room and at increasing temperature and further stress the influence of the substrate, in particular cysteine, on the interlayer. EXAFS studies suggest that Cd(II) coordinates with oxygen atoms, to give monomer complexes or CdO molecules, either on the mineral surface and/or in the interlayer. For Cd-cysteine complexes EXAFS data agree with the existence of Cd-S clusters, thus suggesting a predominant role of the thiol group in the bonding of Cd with the amino acid. (literal)
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