Microscopic single particle characterization of zeolites synthesized in a soil polluted by copper or cadmium and treated with coal fly ash (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Microscopic single particle characterization of zeolites synthesized in a soil polluted by copper or cadmium and treated with coal fly ash (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.clay.2006.07.005 (literal)

Alternative label

• Terzano R; Spagnuolo M; Medici L; Dorriné W; Janssens K; Ruggiero P (2007)
  Microscopic single particle characterization of zeolites synthesized in a soil polluted by copper or cadmium and treated with coal fly ash
  in Applied clay science (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Terzano R; Spagnuolo M; Medici L; Dorriné W; Janssens K; Ruggiero P (literal)

Pagina inizio

• 128 (literal)

Pagina fine

• 138 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 35 (literal)

Rivista

• Applied clay science (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 11 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 1-2 (literal)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• (1) Dipartimento di Biologia e Chimica Agroforestale ed Ambientale, Università degli Studi di Bari, Via Amendola, 165/A, I-70126 Bari, Italy (2) Consiglio Nazionale delle Ricerche (CNR), Istituto di Metodologie per l'Analisi Ambientale (IMAA), Contrada S. Loja, I-85050 Tito Scalo (Potenza), Italy (3) Department of Chemistry, University of Antwerp, Universiteitsplein 1, B-2610 Antwerp, Belgium (literal)

Titolo

• Microscopic single particle characterization of zeolites synthesized in a soil polluted by copper or cadmium and treated with coal fly ash (literal)

Abstract

• In the perspective of the development of new soil remediation technologies, zeolites can be directly synthesized in soil from fused coal fly ash to reduce heavy metal mobility and availability. Such a process promotes the formation of metal hydroxide/oxide precipitates which can be also occluded inside the structure of the forming minerals. In this study, different types of zeolites (zeolite X, P, and A) were synthesized by treating soil samples, artificially contaminated by high concentrations of Cu or Cd ions, with fused coal fly ash at 30 and 60 degrees C. The formed zeolites were characterized for their amount, structure, chemical composition and size. To accomplish this survey, besides quantitative X-ray diffraction analyses (XRD), an automated single particle analysis (ASPA) method using electron probe X-ray microanalysis (EPXMA) was employed for the first time for direct zeolite characterization in soil samples. The obtained results provide new information for assessing the role of heavy metals in zeolite crystallization in coal fly ash-treated soils. Heavy metal contamination, while not significantly hindering the zeolite formation process, can influence crystal size and preferentially drive zeolite synthesis toward the formation of sodalite unit-based zeolite X and zeolite A, even at 60 degrees C. The presence and nature of metal precipitate occlusions inside the forming zeolite minerals might have also favored the preferential synthesis of certain zeolitic structures. (literal)

Prodotto di

• Applicazioni delle Osservazioni della Terra per il monitoraggio ambientale, il controllo del territorio e la protezione dei rischi: genesi, proprietà e valorizzazione dei materiali argillosi (TA.P04.014.003) (Modulo)
• Istituto di metodologie per l'analisi ambientale (IMAA) (Istituto)

Autore CNR

• LUCA MEDICI (Persona)

Insieme di parole chiave

• Keywords of "Microscopic single particle characterization of zeolites synthesized in a soil polluted by copper or cadmium and treated with coal fly ash" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di metodologie per l'analisi ambientale (IMAA) (Istituto)
• Applicazioni delle Osservazioni della Terra per il monitoraggio ambientale, il controllo del territorio e la protezione dei rischi: genesi, proprietà e valorizzazione dei materiali argillosi (TA.P04.014.003) (Modulo)

Autore CNR di

• LUCA MEDICI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Applied clay science (Rivista)

Insieme di parole chiave di

• Keywords of "Microscopic single particle characterization of zeolites synthesized in a soil polluted by copper or cadmium and treated with coal fly ash" (Insieme di parole chiave)