O 1s excitation and ionization processes in the CO2 molecule studied via detection of low-energy fluorescence emission (Articolo in rivista)

Type
Label
  • O 1s excitation and ionization processes in the CO2 molecule studied via detection of low-energy fluorescence emission (Articolo in rivista) (literal)
Anno
  • 2011-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1088/0953-4075/44/16/165103 (literal)
Alternative label
  • A. Kivimäki, J. Alvarez-Ruiz, T.J. Wasowicz, C. Callegari, M. de Simone, M. Alagia, R. Richter, M. Coreno (2011)
    O 1s excitation and ionization processes in the CO2 molecule studied via detection of low-energy fluorescence emission
    in Journal of physics. B, Atomic molecular and optical physics (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • A. Kivimäki, J. Alvarez-Ruiz, T.J. Wasowicz, C. Callegari, M. de Simone, M. Alagia, R. Richter, M. Coreno (literal)
Pagina inizio
  • 165103 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 44 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 11 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR-IOM, Italy; Universidad Politécnica de Madrid, Spain; Gda?sk University of Technology, Poland; Sincrotrone Trieste, Italy; CNR-IMIP, Italy (literal)
Titolo
  • O 1s excitation and ionization processes in the CO2 molecule studied via detection of low-energy fluorescence emission (literal)
Abstract
  • Oxygen 1s excitation and ionization processes in the CO2 molecule have been studied with dispersed and non-dispersed fluorescence spectroscopy as well as with the vacuum ultraviolet (VUV) photon-photoion coincidence technique. The intensity of the neutral O emission line at 845 nm shows particular sensitivity to core-to-Rydberg excitations and core-valence double excitations, while shape resonances are suppressed. In contrast, the partial fluorescence yield in the wavelength window 300-650 nm and the excitation functions of selected O+ and C+ emission lines in the wavelength range 400-500 nm display all of the absorption features. The relative intensity of ionic emission in the visible range increases towards higher photon energies, which is attributed to O 1s shake-off photoionization. VUV photon-photoion coincidence spectra reveal major contributions from the C+ and O+ ions and a minor contribution from C2 +. No conclusive changes in the intensity ratios among the different ions are observed above the O 1s threshold. The line shape of the VUV-O+ coincidence peak in the mass spectrum carries some information on the initial core excitation. (literal)
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