http://www.cnr.it/ontology/cnr/individuo/prodotto/ID34553
Effect of the charge localization in the C$^{+}$-H$^{+}$ fragmentation pathway of the ethyne dication (Articolo in rivista)
- Type
- Label
- Effect of the charge localization in the C$^{+}$-H$^{+}$ fragmentation pathway of the ethyne dication (Articolo in rivista) (literal)
- Anno
- 2011-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1103/PhysRevA.83.014501 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- R. Flammini; M. Satta; E. Fainelli, L. Avaldi (literal)
- Pagina inizio
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- 1
CNR-IMIP, Istituto di Metodologie Inorganiche e dei Plasmi, Area della Ricerca di Roma 1, Via Salaria km 29.300 CP10,
I-00016 Monterotondo Scalo, Rome, Italy
2
CNR-ISMN Istituto dei Materiali Nanostrutturati, Via dei Taurini 19, I-00185 Rome, Italy (literal)
- Titolo
- Effect of the charge localization in the C$^{+}$-H$^{+}$ fragmentation pathway of the ethyne dication (literal)
- Abstract
- The C+ -H+ channel in the fragmentation of the ethyne dication following inner-shell ionization has been
studied by Auger electron-ion-ion coincidence spectroscopy. The ion-ion coincidence map shows a peculiar
feature which corresponds to the emission of both the H+ and C+ ions in the same direction. The analysis of the
data, complemented by ab initio calculations, suggests an interpretation in terms of a two-step, asynchronous
concerted reaction, in which the charge of the ethynyl intermediate ion localizes on the terminal carbon atom. (literal)
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- Autore CNR
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