Self-assembly of nanostructured polymetallaynes (Articolo in rivista)

Type
Label
  • Self-assembly of nanostructured polymetallaynes (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Alternative label
  • Fratoddi, I; Gohlke, C; Cametti, C; Diociaiuti, M; Russo, MV (2008)
    Self-assembly of nanostructured polymetallaynes
    in Polymer (Guildford)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Fratoddi, I; Gohlke, C; Cametti, C; Diociaiuti, M; Russo, MV (literal)
Pagina inizio
  • 3211 (literal)
Pagina fine
  • 3216 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 49 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • \"[Fratoddi, I.; Russo, M. V.] Univ Roma La Sapienza, Dept Chem, I-00185 Rome, Italy; [Gohlke, C.] Univ Calif Irvine, Dept Biomed Engn, Irvine, CA USA; [Cametti, C.] Univ Roma La Sapienza, Dept Phys, I-00185 Rome, Italy; [Cametti, C.] Unita Roma 1, SOFT, CRS, INFM, Rome, Italy; [Diociaiuti, M.] Ist Super Sanita, Dept Technol & Hlth, I-00161 Rome, Italy (literal)
Titolo
  • Self-assembly of nanostructured polymetallaynes (literal)
Abstract
  • Organometallic conjugated polymers containing transition metal centers in the main chain (polymetallynes), with general formula -[M-(PBu3)(2)-C C-X-C C-](n)- with M=Pt(II) and Pd(II), X = organic conjugated spacer, namely poly[ 1,1'-bis(ethynyl)-4,4'-biphenyl-(bis-tributylphosphine)Pd(II)] (Pd-DEBP), poly[1,1'-bis(ethynyl)-4,4'-biphenyl-(bis-tributylphosphine)Pt(II)] (Pt-DEBP) and poly-[1,4-bis(ethynyl)-2,5-dihexadecyloxybenzene-bis(triphenylphosphine)platinum(II)] (Pt-BOB) were synthesized and fully characterized. The polymeric compounds were cast deposited onto glass substrates and their morphologies studied by means of SEM (Scanning Electron Microscopy) and EF-TEM (Energy Filtered-Transmission Electron Microscopy). The formation of nanostructured fibrils with diameters in the range 100-300 nm was revealed by SEM. EF-TEM images showed that the fibers are made of hollow nanotubes, randomly oriented, with external diameter of about 6-7 nm. (C) 2008 Elsevier Ltd. All rights reserved. (literal)
Autore CNR
Insieme di parole chiave

Incoming links:


Autore CNR di
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
Insieme di parole chiave di
data.CNR.it