http://www.cnr.it/ontology/cnr/individuo/prodotto/ID33031
A Tetrahomodioxacalix[6]arene as a Ditopic Ligand for Uranyl Ions with Carbonate or Carbamate Bridges (Articolo in rivista)
- Type
- Label
- A Tetrahomodioxacalix[6]arene as a Ditopic Ligand for Uranyl Ions with Carbonate or Carbamate Bridges (Articolo in rivista) (literal)
- Anno
- 2003-01-01T00:00:00+01:00 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Masci B., Thuéry P. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Titolo
- A Tetrahomodioxacalix[6]arene as a Ditopic Ligand for Uranyl Ions with Carbonate or Carbamate Bridges (literal)
- Abstract
- The first crystal structures of a p-tert-butyltetrahomodioxacalix[6]arene comprising two triphenolic subunits separated by two ether bridges and two of its complexes with uranyl ions are reported. The doubly deprotonated macrocycle assumes a much elongated, cone-like conformation including two organic species. Two binuclear uranyl complexes are described. In both, each cation is bound to the three phenoxide O atoms of a tri-phenolic subunit and to a central, bridging, carbonate or carbamate ion. The formation of the latter ions from the amines used as bases is discussed. (literal)
- Prodotto di
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