An old workhorse for new applications: Fe(dpm)3 as precursor for low-temperature PECVD of iron(III) oxide (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• An old workhorse for new applications: Fe(dpm)3 as precursor for low-temperature PECVD of iron(III) oxide (Articolo in rivista) (literal)

Anno

• 2015-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1039/c5cp00435g (literal)

Alternative label

• Carraro G.; Maccato C.; Gasparotto A.; Barreca D.; Walter M.; Mayrhofer L.; Moseler M.; Venzo A.; Seraglia R.; Marega C. (2015)
  An old workhorse for new applications: Fe(dpm)3 as precursor for low-temperature PECVD of iron(III) oxide
  in Physical chemistry chemical physics (Online)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Carraro G.; Maccato C.; Gasparotto A.; Barreca D.; Walter M.; Mayrhofer L.; Moseler M.; Venzo A.; Seraglia R.; Marega C. (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni

• Autori stranieri (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.rsc.org/en/content/articlelanding/2015/cp/c5cp00435g#!divAbstract (literal)

Rivista

• Physical chemistry chemical physics (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1-3,10 : Department of Chemistry, Padova University and INSTM, 35131 Padova, Italy / 4,8,9 : CNR-IENI and INSTM, Department of Chemistry, Padova University,35131 Padova, Italy / 5-7 : Fraunhofer Institute for Mechanics of Materials, 79108 Freiburg, Germany / 5-7 : Freiburg Materials Research Center, Freiburg University, 79104 Freiburg, Germany (literal)

Titolo

• An old workhorse for new applications: Fe(dpm)3 as precursor for low-temperature PECVD of iron(III) oxide (literal)

Abstract

• An iron(III) beta-diketonate complex, Fe(dpm)3 (Hdpm = 2,2,6,6-tetramethyl-3,5-heptanedione), has been investigated as a potential precursor for plasma enhanced chemical vapor deposition (PECVD) of iron(III) oxide nanomaterials. Thanks to the combined experimental-theoretical approach, spectroscopic properties, spin state, thermal behavior and fragmentation pathways of Fe(dpm)3 have been carefully analysed, obtaining an excellent agreement between simulation and experiment. Preliminary PECVD tests evidenced the possibility of obtaining pure and homogeneous Fe2O3 deposits with controlled nano-organization at temperatures as low as 100°C, even on flexible plastic substrates. The present results open up intriguing perspectives for the exploitation of Fe(dpm)3 as an efficient molecular source for the preparation of nanostructured iron(III) oxides to be used in energetics and gas sensing applications. (literal)

Prodotto di

• Progettazione di Nuovi Precursori Molecolari per Nanosistemi e Ottimizzazione del Processo MOCVD per la Fabbricazione e/o Modifica delle Funzionalità delle Superfici (PM.P05.001.001) (Modulo)
• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)

Autore CNR

• DAVIDE BARRECA (Persona)
• ROBERTA SERAGLIA (Persona)

Insieme di parole chiave

• Parole chiave di "An old workhorse for new applications: Fe(dpm)3 as precursor for low-temperature PECVD of iron(III) oxide" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• DAVIDE BARRECA (Persona)
• ROBERTA SERAGLIA (Persona)
• http://www.cnr.it/ontology/cnr/individuo/unitaDiPersonaleEsterno/ID26616

Prodotto

• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Progettazione di Nuovi Precursori Molecolari per Nanosistemi e Ottimizzazione del Processo MOCVD per la Fabbricazione e/o Modifica delle Funzionalità delle Superfici (PM.P05.001.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Physical chemistry chemical physics (Rivista)

Insieme di parole chiave di

• Parole chiave di "An old workhorse for new applications: Fe(dpm)3 as precursor for low-temperature PECVD of iron(III) oxide" (Insieme di parole chiave)