ENTHALPY OF MIXING WITH H-BONDS INTERACTIONS - THE ROLE OF THE REACTIONAL CONTRIBUTIONS (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• ENTHALPY OF MIXING WITH H-BONDS INTERACTIONS - THE ROLE OF THE REACTIONAL CONTRIBUTIONS (Articolo in rivista) (literal)

Anno

• 1991-01-01T00:00:00+01:00 (literal)

Alternative label

• FRANCESCONI, R; CASTELLARI, C; COMELLI, F; BANDINI, E (1991)
  ENTHALPY OF MIXING WITH H-BONDS INTERACTIONS - THE ROLE OF THE REACTIONAL CONTRIBUTIONS
  in Zeitschrift für physikalische Chemie (N. F.)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• FRANCESCONI, R; CASTELLARI, C; COMELLI, F; BANDINI, E (literal)

Pagina inizio

• 37 (literal)

Pagina fine

• 51 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 173 (literal)

Rivista

• Zeitschrift für physikalische Chemie (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 15 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Consiglio Nazionale delle Ricerche (CNR); IST COMPOSTI CARBONIO (literal)

Titolo

• ENTHALPY OF MIXING WITH H-BONDS INTERACTIONS - THE ROLE OF THE REACTIONAL CONTRIBUTIONS (literal)

Abstract

• A theoretical model is given to split the experimental heat of mixing into contributions from pure mixing and chemical reactions, when associations between the components occur in the binary system. The mixtures studied in this paper are 1,3-dioxolane + acetic acid and 1,3-dioxolane + trichloroethylene, whose calorimetric data were obtained previously. To obtain a realistic association pattern, NMR measurements are carried out. The mixtures were assumed non-ideal, and an extended regular solution model was used to calculate the activity coefficients of each component. From the comparison between experimental and calculated heats of mixing, the equilibrium constants of association reactions are calculated. The reliability of the fit is discussed. (literal)

Prodotto di

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Sintesi e caratterizzazione mediante metodologie chimiche innovative, di scaffold molecolari per l'individuazione di nuove molecole biologicamente attive. (PM.P03.011.002) (Modulo)

Autore CNR

• ELISA BANDINI (Unità di personale interno)

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• Parole chiave di "ENTHALPY OF MIXING WITH H-BONDS INTERACTIONS - THE ROLE OF THE REACTIONAL CONTRIBUTIONS" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Sintesi e caratterizzazione mediante metodologie chimiche innovative, di scaffold molecolari per l'individuazione di nuove molecole biologicamente attive. (PM.P03.011.002) (Modulo)

Autore CNR di

• ELISA BANDINI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Zeitschrift für physikalische Chemie (Rivista)

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• Parole chiave di "ENTHALPY OF MIXING WITH H-BONDS INTERACTIONS - THE ROLE OF THE REACTIONAL CONTRIBUTIONS" (Insieme di parole chiave)