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Structural properties and multiferroic phase diagram of Ksub/0.6/Fesub/0.6/sup/II/Fesub/0.4/sup/III/Fsub/3/ fluoride with TTB structure (Articolo in rivista)
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- Structural properties and multiferroic phase diagram of Ksub/0.6/Fesub/0.6/sup/II/Fesub/0.4/sup/III/Fsub/3/ fluoride with TTB structure (Articolo in rivista) (literal)
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- 2008-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1103/PhysRevB.78.064111 (literal)
- Alternative label
Mezzadri F.; Fabbrici S.; Montanari E.; Righi L.; Calestani G.; Gilioli E.; Bolzoni F.; Migliori A. (2008)
Structural properties and multiferroic phase diagram of Ksub/0.6/Fesub/0.6/sup/II/Fesub/0.4/sup/III/Fsub/3/ fluoride with TTB structure
in Physical review. B, Condensed matter and materials physics (Online); APS, American physical society, College Park, MD (Stati Uniti d'America)
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- Mezzadri F.; Fabbrici S.; Montanari E.; Righi L.; Calestani G.; Gilioli E.; Bolzoni F.; Migliori A. (literal)
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- http://prb.aps.org/abstract/PRB/v78/i6/e064111 (literal)
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- In: Physical Review B, vol. 78 article n. 064111. The American Physical Society, 2008. (literal)
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- University of Parma, Parma, Italy, University of Parma, Parma Italy and CNR-IMEM, Parma, CNR-IMM, Bologna (literal)
- Titolo
- Structural properties and multiferroic phase diagram of Ksub/0.6/Fesub/0.6/sup/II/Fesub/0.4/sup/III/Fsub/3/ fluoride with TTB structure (literal)
- Abstract
- Iron fluorides with tetragonal tungsten bronze (TTB) structure, having general formula of Ksub/x/Fesub/x/sup/II/Fesub/1-x/sup/III/Fsub/3/ with 0.4x0.6, are possible candidates for complete multiferroism (elastic, electric, and magnetic orders)coupled with charge ordering phenomena. Following the indication of a previous general work, we concentrated our attention on the potassium rich region of these bronzes where an orthorhombic distortion of the fundamental TTB structure takes place. We tried to define the complex phase diagram of Ksub/0.6/FeFsub/3/, involving the different ordering phenomena in the range of 5-600 K, by using a series of characterization techniques such as transmission electron microscopy, x-ray and neutron diffractions, and magnetic measurements. The results revealed the coexistence of all these orders below the magnetic transition occurring at 118 K, showing the unique behavior of a system that can be considered a model for multiferroism. (literal)
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