Ethylene decomposition at undercoordinated sites on Cu(410) (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Ethylene decomposition at undercoordinated sites on Cu(410) (Articolo in rivista) (literal)

Anno

• 2008-01-01T00:00:00+01:00 (literal)

Alternative label

• Kravchuk T.; Vattuone L.; Burkholder L.; Tysoe W. T.; Rocca M. (2008)
  Ethylene decomposition at undercoordinated sites on Cu(410)
  in Journal of the American Chemical Society (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Kravchuk T.; Vattuone L.; Burkholder L.; Tysoe W. T.; Rocca M. (literal)

Pagina inizio

• 12552 (literal)

Pagina fine

• 12553 (literal)

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• 130 (literal)

Rivista

• Journal of the American Chemical Society (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• In: Journal of the American Chemical Society, vol. 130 pp. 12552 - 12553. American Chemical Society, 2008. (literal)

Note

• ISI Web of Science (WOS) (literal)

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• Dipartimento di Fisica Genova e CNISM, Department of Chemistry and Biochemistry, University of Wisconsin-Milwaukee, CNR-IMEM, Parma and Dipartimento di Fisica, Università diGenova (literal)

Titolo

• Ethylene decomposition at undercoordinated sites on Cu(410) (literal)

Abstract

• We demonstrate the selective, low-temperature chemistry of ethylene on the strongly undercoordinated sites of Cu(410) by investigating its adsorption by high-resolution electron energy loss spectroscopy (HREELS), X-ray photoelectron spectroscopy (XPS), and temperature-programmed desorption (TPD). After dosing ethylene at 110 K, apart from the expected p-bonded species adsorbed on terraces, di-s-bonded ethylene and carbon are formed at the step edges. The latter product results from the complete dehydrogenation of ethylene and blocks sites for further dissociation and/or di-s-adsorption. However, these processes can be restored merely by heating the sample to 900 K, by causing the carbon to diffuse into the bulk. The presented results support the relevance of copper-based catalysts for the steam reforming process. (literal)

Prodotto di

• Proprietà delle superfici e dei cluster di materiali nanostrutturati (MD.P06.002.001) (Modulo)
• Istituto dei materiali per l'elettronica ed il magnetismo (IMEM) (Istituto)

Autore CNR

• MARIO AGOSTINO ROCCA (Persona)
• Luca Vattuone (Persona)

Insieme di parole chiave

• Keywords of "Ethylene decomposition at undercoordinated sites on Cu(410)" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto dei materiali per l'elettronica ed il magnetismo (IMEM) (Istituto)
• Proprietà delle superfici e dei cluster di materiali nanostrutturati (MD.P06.002.001) (Modulo)

Autore CNR di

• MARIO AGOSTINO ROCCA (Persona)
• Luca Vattuone (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of the American Chemical Society (Rivista)

Insieme di parole chiave di

• Keywords of "Ethylene decomposition at undercoordinated sites on Cu(410)" (Insieme di parole chiave)