Ionization Energy and Energy Gap Structure of MoSI Molecular Wires: Kelvin Probe, Ultraviolet Photoelectron Spectroscopy, and Cyclic Voltammetry Measurements (Articolo in rivista)

Type
Label
  • Ionization Energy and Energy Gap Structure of MoSI Molecular Wires: Kelvin Probe, Ultraviolet Photoelectron Spectroscopy, and Cyclic Voltammetry Measurements (Articolo in rivista) (literal)
Anno
  • 2011-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/la1050767 (literal)
Alternative label
  • Strojnik, Martin; Omerzu, Ales; Majkic, Aleksej; Mihailovic, Peter M.; Lukan, Junos; Bavdek, Gregor; Bratina, Gvido; Cvetko, Dean; Topolovsek, Peter; Mihailovic, Dragan (2011)
    Ionization Energy and Energy Gap Structure of MoSI Molecular Wires: Kelvin Probe, Ultraviolet Photoelectron Spectroscopy, and Cyclic Voltammetry Measurements
    in Langmuir
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Strojnik, Martin; Omerzu, Ales; Majkic, Aleksej; Mihailovic, Peter M.; Lukan, Junos; Bavdek, Gregor; Bratina, Gvido; Cvetko, Dean; Topolovsek, Peter; Mihailovic, Dragan (literal)
Pagina inizio
  • 4296 (literal)
Pagina fine
  • 4299 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 27 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 4 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 8 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Jozef Stefan Institute; University of Nova Gorica; University of Ljubljana; Cnr Iom; University of Ljubljana; CENN Nanoctr (literal)
Titolo
  • Ionization Energy and Energy Gap Structure of MoSI Molecular Wires: Kelvin Probe, Ultraviolet Photoelectron Spectroscopy, and Cyclic Voltammetry Measurements (literal)
Abstract
  • The work function W of Mo6S3I6 molecular nanowires is determined by Kelvin probe (KP) measurements, UV photoelectron spectroscopy (UPS), and cyclic voltammetry (CV). The values obtained by all three methods agree well, giving W = 4.8 +/- 0.1 eV. CV measurements also give a gap between the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) of Eg = 1.2 +/- 0.1 eV, in agreement with recent optical measurements, but in disagreement with theoretical calculations, which predictict the materials to be a metal. The electronic structure of Mo6S3I6 suggests use of the material in applications such as bulk heterostructure photovoltaics and transparent electrodes and for molecular electronics devices. (literal)
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