In Situ X-Ray Spectromicroscopy Investigation of the Material Stability of SOFC Metal Interconnects in Operating Electrochemical Cells (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• In Situ X-Ray Spectromicroscopy Investigation of the Material Stability of SOFC Metal Interconnects in Operating Electrochemical Cells (Articolo in rivista) (literal)

Anno

• 2011-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/cssc.201100140 (literal)

Alternative label

• Bozzini, Benedetto; Tondo, Elisabetta; Prasciolu, Mauro; Amati, Matteo; Abyaneh, Majid Kazemian; Gregoratti, Luca; Kiskinova, Maya (2011)
  In Situ X-Ray Spectromicroscopy Investigation of the Material Stability of SOFC Metal Interconnects in Operating Electrochemical Cells
  in ChemSusChem (Weinh., Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Bozzini, Benedetto; Tondo, Elisabetta; Prasciolu, Mauro; Amati, Matteo; Abyaneh, Majid Kazemian; Gregoratti, Luca; Kiskinova, Maya (literal)

Pagina inizio

• 1099 (literal)

Pagina fine

• 1103 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 4 (literal)

Rivista

• ChemSusChem (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 5 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 8 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• University of Salento; CNR IOM; Sincrotrone Trieste (literal)

Titolo

• In Situ X-Ray Spectromicroscopy Investigation of the Material Stability of SOFC Metal Interconnects in Operating Electrochemical Cells (literal)

Abstract

• The present in situ study of electrochemically induced processes occurring in Cr/Ni bilayers in contact with a YSZ electrolyte aims at a molecular-level understanding of the fundamental aspects related to the durability of metallic interconnects in solid oxide fuel cells (SOFCs). The results demonstrate the potential of scanning photoelectron microspectroscopy and imaging to follow in situ the evolution of the chemical states and lateral distributions of the constituent elements (Ni, Cr, Zr, and Y) as a function of applied cathodic potential in a cell working at 650 degrees C in 10(-6) mbar O(2) ambient conditions. The most interesting findings are the temperature-induced and potential-dependent diffusion of Ni and Cr, and the oxidation-reduction processes resulting in specific morphology-composition changes in the Ni, Cr, and YSZ areas. (literal)

Prodotto di

• MD.P06.017.001 Nanofabbricazione (MD.P06.017.005) (Modulo)

Autore CNR

• MAURO PRASCIOLU (Persona)

Insieme di parole chiave

• Parole chiave di "In Situ X-Ray Spectromicroscopy Investigation of the Material Stability of SOFC Metal Interconnects in Operating Electrochemical Cells" (Insieme di parole chiave)

Incoming links:

Prodotto

• MD.P06.017.001 Nanofabbricazione (MD.P06.017.005) (Modulo)

Autore CNR di

• MAURO PRASCIOLU (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• ChemSusChem (Rivista)

Insieme di parole chiave di

• Parole chiave di "In Situ X-Ray Spectromicroscopy Investigation of the Material Stability of SOFC Metal Interconnects in Operating Electrochemical Cells" (Insieme di parole chiave)