http://www.cnr.it/ontology/cnr/individuo/prodotto/ID323436

A Ruthenium-Based Catalytic System for a Mild Borrowing-Hydrogen Process (Articolo in rivista)

Type

Label

A Ruthenium-Based Catalytic System for a Mild Borrowing-Hydrogen Process (Articolo in rivista) (literal)

Anno

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

Alternative label

Jumde, Varsha R.; Gonsalvi, Luca; Guerriero, Antonella; Peruzzini, Maurizio; Taddei, Maurizio (2015)
A Ruthenium-Based Catalytic System for a Mild Borrowing-Hydrogen Process
in European journal of organic chemistry (Print); WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim (Germania)
(literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

Jumde, Varsha R.; Gonsalvi, Luca; Guerriero, Antonella; Peruzzini, Maurizio; Taddei, Maurizio (literal)

Pagina inizio

Pagina fine

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

http://www.scopus.com/record/display.url?eid=2-s2.0-84922882953&origin=inward (literal)

Rivista

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

Note

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

Universita degli Studi di Siena; Istituto Di Chimica Dei Composti Organometallici, Sesto Fiorentino (literal)

Titolo

A Ruthenium-Based Catalytic System for a Mild Borrowing-Hydrogen Process (literal)

Abstract

The alkylation of arylamines using stoichiometric amounts of aliphatic and benzylic alcohols in the presence of tBuOK was carried out at 55 °C using a low catalyst loading of [Ru(cod)Cl2]n/PTA (1,3,5-triaza-7-phosphaadamantane). The overall borrowing-hydrogen process does not require a controlled nitrogen atmosphere, and it could also be carried out at room temperature using higher loading of base. A wide range of substrates can be used in this transformation, and it has a good tolerance of different substituents. This catalytic system proved also to be efficient for other hydrogen-transfer reactions such as a tandem oxidation/C-C coupling between 1-phenylethanol and primary alcohols. (literal)

Editore