Synthesis, crystal structure, thermal analysis and magnetic behaviour of a novel one-dimensional polymeric pyridinium chlorocuprate(II): (Hpy)2[Cu3Cl8(H2O)2] (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Synthesis, crystal structure, thermal analysis and magnetic behaviour of a novel one-dimensional polymeric pyridinium chlorocuprate(II): (Hpy)2[Cu3Cl8(H2O)2] (Articolo in rivista) (literal)

Anno

• 2003-01-01T00:00:00+01:00 (literal)

Alternative label

• Bhattacharya R., Ghosh A., Ray M.S., Righi L., Bocelli G., Chaudhuri S., Willet R.D., Clemente-Juan J.M., Cornado E., Gomez-Garcia C.J. (2003)
  Synthesis, crystal structure, thermal analysis and magnetic behaviour of a novel one-dimensional polymeric pyridinium chlorocuprate(II): (Hpy)2[Cu3Cl8(H2O)2]
  in European journal of inorganic chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Bhattacharya R., Ghosh A., Ray M.S., Righi L., Bocelli G., Chaudhuri S., Willet R.D., Clemente-Juan J.M., Cornado E., Gomez-Garcia C.J. (literal)

Pagina inizio

• 4253 (literal)

Pagina fine

• 4259 (literal)

Rivista

• European journal of inorganic chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Titolo

• Synthesis, crystal structure, thermal analysis and magnetic behaviour of a novel one-dimensional polymeric pyridinium chlorocuprate(II): (Hpy)2[Cu3Cl8(H2O)2] (literal)

Abstract

• A one-dimensional polymeric pyridinium chlorocuprate (HPy)2[Cu3Cl8(H2O)2], an intermediate between (HPy)CuCl3 and CuCl2·2H2O, has been synthesized and characterized by X-ray analysis. The structure contains [Cu3Cl8(H2O)2]n2n- chains in which both square-pyramidal and octahedral CuII exist. The chains are composed of linked [Cu2Cl6]2- dimers and CuCl2(H2O)2 monomeric units. On being heated in the solid state the compound undergoes dehydration followed by dehydrohalogenation to produce a pyridine complex of CuII: [Cu3Py2Cl6]. Magnetic studies reveal ferromagnetic coupling within the chains with an intradimer exchange coupling of 12.1 cm-1 and a dimer-monomer exchange coupling of 1.34 cm-1. (literal)

Prodotto di

• Istituto dei materiali per l'elettronica ed il magnetismo (IMEM) (Istituto)

Autore CNR

• GABRIELE BOCELLI (Unità di personale interno)

Incoming links:

Prodotto

• Istituto dei materiali per l'elettronica ed il magnetismo (IMEM) (Istituto)

Autore CNR di

• GABRIELE BOCELLI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• European journal of inorganic chemistry (Rivista)