Synthesis, characterisation and X-ray crystal structure of copper(II) complexes with unsym-metrical tetradentate Shiff base ligand: first evidence of Cu(II) catalysed rearrangement of unsymmetrical to symmetrical complex (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Synthesis, characterisation and X-ray crystal structure of copper(II) complexes with unsym-metrical tetradentate Shiff base ligand: first evidence of Cu(II) catalysed rearrangement of unsymmetrical to symmetrical complex (Articolo in rivista) (literal)

Anno

• 2003-01-01T00:00:00+01:00 (literal)

Alternative label

• Ray M.S., Bhattacharya R., Chaudhuri S., Righi L., Bocelli G., Mukhopadhyay G., Ghosh A. (2003)
  Synthesis, characterisation and X-ray crystal structure of copper(II) complexes with unsym-metrical tetradentate Shiff base ligand: first evidence of Cu(II) catalysed rearrangement of unsymmetrical to symmetrical complex
  in Polyhedron
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Ray M.S., Bhattacharya R., Chaudhuri S., Righi L., Bocelli G., Mukhopadhyay G., Ghosh A. (literal)

Pagina inizio

• 617 (literal)

Pagina fine

• 624 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 22 (literal)

Rivista

• Polyhedron (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Titolo

• Synthesis, characterisation and X-ray crystal structure of copper(II) complexes with unsym-metrical tetradentate Shiff base ligand: first evidence of Cu(II) catalysed rearrangement of unsymmetrical to symmetrical complex (literal)

Abstract

• The mononuclear copper(II) complexes, [CuL1](ClO4) and [CuL2](ClO4) with unsymmetrical quadridentate Schiff base ligands have been prepared and characterised. The second complex undergoes Cu(II)/H+ catalysed rearrangement to [CuL3](ClO4)2 where L3 is a symmetrical tetradentate Schiff base involving 1,3-propanediamine and pyridine-2-carboxaldehyde. Structures of all the three compounds have been verified by single crystal X-ray analysis. The geometry around Cu(II) is square-planar in the first and second complexes whereas that in the three is distorted octahedral. (literal)

Prodotto di

• Istituto dei materiali per l'elettronica ed il magnetismo (IMEM) (Istituto)

Autore CNR

• GABRIELE BOCELLI (Unità di personale interno)

Incoming links:

Prodotto

• Istituto dei materiali per l'elettronica ed il magnetismo (IMEM) (Istituto)

Autore CNR di

• GABRIELE BOCELLI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Polyhedron (Rivista)