Crystal structure, magnetic and thermal properties of the one-dimensional complex [Nd(pzam)(3)(H2O)Mo(CN)(8)] center dot H2O (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Crystal structure, magnetic and thermal properties of the one-dimensional complex [Nd(pzam)(3)(H2O)Mo(CN)(8)] center dot H2O (Articolo in rivista) (literal)

Anno

• 2008-01-01T00:00:00+01:00 (literal)

Alternative label

• Tanase, S; Evangelisti, M; de Jongh, LJ; Smits, JMM; de Gelder, R (2008)
  Crystal structure, magnetic and thermal properties of the one-dimensional complex [Nd(pzam)(3)(H2O)Mo(CN)(8)] center dot H2O
  in Inorganica Chimica Acta (Testo stamp.)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Tanase, S; Evangelisti, M; de Jongh, LJ; Smits, JMM; de Gelder, R (literal)

Pagina inizio

• 3548 (literal)

Pagina fine

• 3554 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 361 (literal)

Rivista

• Inorganica Chimica Acta (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• \"[Tanase, Stefania] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands; [Evangelisti, Marco] Natl Res Ctr NanoStruct & BioSyst Surfaces S3, CNR, INFM, I-41100 Modena, Italy; [de Jongh, L. Jos] Leiden Univ, Leiden Inst Phys, Kamerlingh Onnes Lab, NL-2300 RA Leiden, Netherlands; [Smits, Jan M. M.; de Gelder, Rene] Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 ED Nijmegen, Netherlands (literal)

Titolo

• Crystal structure, magnetic and thermal properties of the one-dimensional complex [Nd(pzam)(3)(H2O)Mo(CN)(8)] center dot H2O (literal)

Abstract

• The new d-f cyanido-bridged 1D assembly [Nd(pzam)(3)(H2O)Mo(CN)(8)]center dot H2O was prepared by self-assembly of pyrazine-2-carboxamide (pzam), Nd(NO3) center dot nH(2)O and (Bu3NH)(3)[Mo(CN)(8)] center dot 4H(2)O in acetonitrile. X-ray crystallographic studies indicate that the complex comprises chains of alternating, cyanido-bridged [Nd(pzam)(3)(H2O)](3+) and Mo(CN)(8)](3) fragments. The magneto-structural properties have been studied by field-dependent magnetization and specific heat measurements at low temperatures (>= 0.3 K). Below approximate to 10 K the Nd(III) moment is well approximated by an effective spin S = 1/2, with anisotropic g-tensor. The exchange coupling between the Nd(III) and the Mo(V) spins S = 1/2 along the structural chains is found to be ferromagnetic, with J/k(B) = 1.8 +/- 0.2 K and approximately XY (planar) anisotropy. No evidence for 3D interchain magnetic ordering is found. A comparison with magneto-structural data of other cyanido-bridged complexes involving the Nd(III) ion is presented. (c) 2008 Elsevier B.V. All rights reserved. (literal)

Prodotto di

• Nanomagnetismo controllo della dinamica della magnetizzazione in nanomagneti (MD.P06.011.001) (Modulo)

Autore CNR

• MARCO EVANGELISTI (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Crystal structure, magnetic and thermal properties of the one-dimensional complex [Nd(pzam)(3)(H2O)Mo(CN)(8)] center dot H2O" (Insieme di parole chiave)

Incoming links:

Prodotto

• Nanomagnetismo controllo della dinamica della magnetizzazione in nanomagneti (MD.P06.011.001) (Modulo)

Autore CNR di

• MARCO EVANGELISTI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganica Chimica Acta (Rivista)

Insieme di parole chiave di

• Keywords of "Crystal structure, magnetic and thermal properties of the one-dimensional complex [Nd(pzam)(3)(H2O)Mo(CN)(8)] center dot H2O" (Insieme di parole chiave)