http://www.cnr.it/ontology/cnr/individuo/prodotto/ID32023
Thermal properties and microhardness of HDPE/clay nanocomposites compatibilized by different functionalized polyethylenes (Articolo in rivista)
- Type
- Label
- Thermal properties and microhardness of HDPE/clay nanocomposites compatibilized by different functionalized polyethylenes (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Alternative label
L. Minkova, Y. Peneva, E. Tashev, S. Filippi, M. Pracella, P. Magagnini (2009)
Thermal properties and microhardness of HDPE/clay nanocomposites compatibilized by different functionalized polyethylenes
in Polymer testing
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- L. Minkova, Y. Peneva, E. Tashev, S. Filippi, M. Pracella, P. Magagnini (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- L. Minkova, Y. Peneva, E. Tashev: Institute of Polymers, Bulgarian Academy of Sciences, Sofia 1113, Bulgaria
S. Filippi, P. Magagnini: Department of Chemical Engineering and Materials Science, University of Pisa, Pisa 56122, Italy
(literal)
- Titolo
- Thermal properties and microhardness of HDPE/clay nanocomposites compatibilized by different functionalized polyethylenes (literal)
- Abstract
- The calorimetric characteristics, the flammability, the thermal stability and the microhardness
of polyethylene high density/clay nanocomposites (HDPE/clay) have been
studied by differential scanning calorimetry, thermogravimetry, determination of limiting
oxygen index and microhardness tests. The nanocomposites have been compatibilized by
ethyleneacrylic acid copolymer (EAA), acrylic acid grafted HDPE (HDAA) and maleic
anhydride grafted HDPE (HDMA). The clay was montmorillonite Cloisite 15A. The influence
of the presence and the type of the compatibilizers on the properties of the nanocomposites
has been evaluated. The results have shown that the thermal stability, the
reduction of the flammability and the microhardness of HDPE/clay nanocomposites,
compatibilized by HDAA and HDMA are higher than those for nanocomposite compatibilized
by EAA. Moreover, the presence and the type of compatibilizer have negligible
effect on the characteristics of the HDPE phase transitions. These results have been
interpreted by the better clay dispersion and higher level of clay exfoliation in the presence
of compatibilizers HDAA and HDMA, than those in the presence of EAA compatibilizer. (literal)
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