Energetics and Hierarchical Interactions of Metal Phthalocyanines Adsorbed on Graphene/Ir(111) (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Energetics and Hierarchical Interactions of Metal Phthalocyanines Adsorbed on Graphene/Ir(111) (Articolo in rivista) (literal)

Anno

• 2013-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/la401850v (literal)

Alternative label

• Scardamaglia, M; Struzzi, C; Lizzit, S; Dalmiglio, M; Lacovig, P; Baraldi, A; Mariani, C; Betti, MG (2013)
  Energetics and Hierarchical Interactions of Metal Phthalocyanines Adsorbed on Graphene/Ir(111)
  in Langmuir
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Scardamaglia, M; Struzzi, C; Lizzit, S; Dalmiglio, M; Lacovig, P; Baraldi, A; Mariani, C; Betti, MG (literal)

Pagina inizio

• 10440 (literal)

Pagina fine

• 10447 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 29 (literal)

Rivista

• Langmuir (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 33 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Univ Roma La Sapienza, Dipartimento Fis, CNISM, CNIS, I-00185 Rome, Italy; Elettra Sincrotrone Trieste, I-34149 Trieste, Italy; Univ Trieste, Phys Deparment, I-34127 Trieste, Italy; Univ Trieste, Ctr Excellence Nanostured Mat, I-34127 Trieste, Italy; ] IOM CNR Lab TASC, I-34012 Trieste, Italy; ] Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy (literal)

Titolo

• Energetics and Hierarchical Interactions of Metal Phthalocyanines Adsorbed on Graphene/Ir(111) (literal)

Abstract

• The adsorption of metal-phthalocyanine (MPc) layers (M = Fe, Co, Cu) assembled on graphene/Ir(111) is studied by means of temperature-programmed X-ray photoemission spectroscopy (XPS) and near-edge X-ray absorption fine structure (NEXAFS). The balance between interaction forces among the organometallic molecules and the underlying graphene gives rise to flat-lying molecular layers, weakly interacting with the underlying graphene. Further MPc layers pile up face-on onto the first layer, up to a few nanometers thickness, as deduced by NEXAFS. The FePc, CoPc, and CuPc multilayers present comparable desorption temperatures, compatible with molecule-molecule interactions dominated by van der Waals forces between the ?-conjugated macrocycles. The MPc single layers desorb from graphene/Ir at higher temperatures. The CuPc single layer desorbs at lower temperature than the FePc and CoPc single layers, suggesting a higher adsorption energy of the FePc and CoPc single layers on graphene/Ir with respect to CuPc, with increasing molecule-substrate interaction in the order ECuPc < EFePc ~ ECoPc. (literal)

Prodotto di

• MD.P06.016.001 Proprieta' elettroniche e strutturali di sistemi a bassa dimensionalita' (MD.P06.016.003) (Modulo)

Autore CNR

• ALESSANDRO BARALDI (Persona)

Incoming links:

Autore CNR di

• ALESSANDRO BARALDI (Persona)

Prodotto

• MD.P06.016.001 Proprieta' elettroniche e strutturali di sistemi a bassa dimensionalita' (MD.P06.016.003) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Langmuir (Rivista)