Role of the Anchored Groups in the Bonding and Self-Organization of Macrocycles: Carboxylic versus Pyrrole Groups (Articolo in rivista)

Type
Label
  • Role of the Anchored Groups in the Bonding and Self-Organization of Macrocycles: Carboxylic versus Pyrrole Groups (Articolo in rivista) (literal)
Anno
  • 2013-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/jp4005949 (literal)
Alternative label
  • Gonzalez-Moreno, Ruben; Garcia-Lekue, Aran; Arnau, Andres; Trelka, Marta; Gallego, Jose M.; Otero, Roberto; Verdini, Alberto; Sanchez-Sanchez, Carlos; de Andres, Pedro L.; Angel Martin-Gago, Jose; Rogero, Celia (2013)
    Role of the Anchored Groups in the Bonding and Self-Organization of Macrocycles: Carboxylic versus Pyrrole Groups
    in Journal of physical chemistry. C
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Gonzalez-Moreno, Ruben; Garcia-Lekue, Aran; Arnau, Andres; Trelka, Marta; Gallego, Jose M.; Otero, Roberto; Verdini, Alberto; Sanchez-Sanchez, Carlos; de Andres, Pedro L.; Angel Martin-Gago, Jose; Rogero, Celia (literal)
Pagina inizio
  • 7661 (literal)
Pagina fine
  • 7668 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 117 (literal)
Rivista
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  • 8 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 15 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Consejo Superior de Investigaciones Cientificas (CSIC); DIPC; Basque Fdn Sci; University of Basque Country; Autonomous University of Madrid; Consejo Superior de Investigaciones Cientificas (CSIC); Inst Madrileno Estudios Avanzados Nanociencia IMD; Consiglio Nazionale delle Ricerche (CNR); Swiss Federal Laboratories for Materials Science & Technology (EMPA); Consejo Superior de Investigaciones Cientificas (CSIC) (literal)
Titolo
  • Role of the Anchored Groups in the Bonding and Self-Organization of Macrocycles: Carboxylic versus Pyrrole Groups (literal)
Abstract
  • A combination of variable temperature scanning tunneling microscopy, near edge X-ray adsorption fine structure and density functional theory has been used to investigate the chemisorption and self-assembly of metal-free protoporphyrin IX molecules on Cu(110) surface. The molecules in contact with the substrate suffer irreversible molecular transformations, mainly deprotonation of the carboxylic groups and metalation of the pyrroline subunits. The carboxylate group has been revealed as the anchored group versus the tetrapyrrole ring. We study the role played by the carboxylic acid groups in the surface-molecular bonding and how its presence affects the supramolecular structure. (literal)
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