NMR-investigation of the mechanism of silver mercaptide thermolysis in amorphous polystyrene (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• NMR-investigation of the mechanism of silver mercaptide thermolysis in amorphous polystyrene (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1039/b613228f (literal)

Alternative label

• Conte, P.; Carotenuto, G.; Piccolo, A.; Perlo, P.; Nicolais L. (2007)
  NMR-investigation of the mechanism of silver mercaptide thermolysis in amorphous polystyrene
  in Journal of materials chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Conte, P.; Carotenuto, G.; Piccolo, A.; Perlo, P.; Nicolais L. (literal)

Pagina inizio

• 201 (literal)

Pagina fine

• 205 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.rsc.org/en/Content/ArticleLanding/2007/JM/b613228f (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 17 (literal)

Rivista

• Journal of materials chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• IMCB - CNR, Napoli Università Federico II di Napoli, Napoli CRF, Torino (literal)

Titolo

• NMR-investigation of the mechanism of silver mercaptide thermolysis in amorphous polystyrene (literal)

Abstract

• Polymer-embedded silver clusters have been prepared by thermal decomposition of silver dodecylmercaptide previously dissolved in amorphous polystyrene. The morphology and structure of silver clusters have been determined by transmission electron microscopy (TEM) and large angle X-ray diffractometry (XRD), respectively. The mechanism involved in the thermolysis reaction was elucidated by different NMR techniques. The thermolysis produced thiol-derivatized silver clusters (i.e., silver clusters coated with a self-organized thiol monolayer, Agx(SC12H25)y) and had the effect of increasing the branching degree of polystyrene due to enhanced cross-linking. (literal)

Prodotto di

• Institute for composite and biomedical materials (IMCB) (Istituto)
• Studio delle proprietà elettroniche di nanofasi confinate in polimero e loro applicazione tecnologica (PM.P07.004.005) (Modulo)

Autore CNR

• GIANFRANCO CAROTENUTO (Persona)

Insieme di parole chiave

• Parole chiave di "NMR-investigation of the mechanism of silver mercaptide thermolysis in amorphous polystyrene" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute for composite and biomedical materials (IMCB) (Istituto)
• Studio delle proprietà elettroniche di nanofasi confinate in polimero e loro applicazione tecnologica (PM.P07.004.005) (Modulo)

Autore CNR di

• GIANFRANCO CAROTENUTO (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of materials chemistry (Rivista)

Insieme di parole chiave di

• Parole chiave di "NMR-investigation of the mechanism of silver mercaptide thermolysis in amorphous polystyrene" (Insieme di parole chiave)