http://www.cnr.it/ontology/cnr/individuo/prodotto/ID317123
Mononuclear copper(I) complexes of O-t-butyl-1,1-dithiooxalate and of O-t-butyl-1-perthio-1-thiooxalate (Articolo in rivista)
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- Mononuclear copper(I) complexes of O-t-butyl-1,1-dithiooxalate and of O-t-butyl-1-perthio-1-thiooxalate (Articolo in rivista) (literal)
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- 2011-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.ica.2011.02.037 (literal)
- Alternative label
Zigler, David F.; Tordin, Elisa; Wu, Guang; Iretskii, Alexei; Cariati, Elena; Ford, Peter C. (2011)
Mononuclear copper(I) complexes of O-t-butyl-1,1-dithiooxalate and of O-t-butyl-1-perthio-1-thiooxalate
in Inorganica Chimica Acta (Testo stamp.); Elsevier, Amsterdam (Paesi Bassi)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Zigler, David F.; Tordin, Elisa; Wu, Guang; Iretskii, Alexei; Cariati, Elena; Ford, Peter C. (literal)
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- University of California Santa Barbara; University of Milan; Ctr CNR ISTM; Lake Super State Univ (literal)
- Titolo
- Mononuclear copper(I) complexes of O-t-butyl-1,1-dithiooxalate and of O-t-butyl-1-perthio-1-thiooxalate (literal)
- Abstract
- Described are the syntheses and structures of a phosphonium salt of the anionic ligand O-t-butyl-1,1-dithiooxalate, [PPh(3)Bz][i-dto(t)Bu] ([PPh3Bz][1]), and of two Cu(I) complexes of this anion, Cu(PPh3)(2)(eta(2)-i-dto(t)Bu) (2) and Cu(dmp)(PPh3)(eta(1)-i-dto(t)Bu) (3, dmp = 2,9-dimethyl-1,10-phenanthroline). In addition, it was found that the reaction of CuBr2 with i-dto(t)Bu gives a O-t-butyl-1-perthio-1-thiooxalato complex of copper(I), [BzPh(3)P][Cu(Br)(S-i-dto(t)Bu)] ([BzPh(3)P][4]), where [S-i-dto(t)Bu] is a disulfide-containing anionic ligand. The electronic structure and absorption spectrum of this species were investigated by time dependent DFT methods. (C) 2011 Elsevier B.V. All rights reserved. (literal)
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