Self-organized Liquid-Crystalline Polyethers obtained by grafting tapered mesogenic groups onto Poly(epichlorohydrin): toward biomimetic ion channels (Articolo in rivista)

Type
Label
  • Self-organized Liquid-Crystalline Polyethers obtained by grafting tapered mesogenic groups onto Poly(epichlorohydrin): toward biomimetic ion channels (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Alternative label
  • Ronda J.C. 1, Reina J.A. 2 , Cádiz V. 3, Giamberini M. 4, Nicolais L. 5 (2003)
    Self-organized Liquid-Crystalline Polyethers obtained by grafting tapered mesogenic groups onto Poly(epichlorohydrin): toward biomimetic ion channels
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Ronda J.C. 1, Reina J.A. 2 , Cádiz V. 3, Giamberini M. 4, Nicolais L. 5 (literal)
Pagina inizio
  • 2918 (literal)
Pagina fine
  • 2929 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 41 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • 4 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1 Universitat Rovira i Virgili Tarragona Spain, 2 Universitat Rovira i Virgili Tarragona Spain, 3 Universitat Rovira i Virgili Tarragona Spain, 4 CNR, 5 CNR (literal)
Titolo
  • Self-organized Liquid-Crystalline Polyethers obtained by grafting tapered mesogenic groups onto Poly(epichlorohydrin): toward biomimetic ion channels (literal)
Abstract
  • A set of high molecular weight new side-chain liquid-crystallyne polyethers was obtained by chemical modification of poly(epichlorodrin) with potassium 3,4,5-tris (dodecyloxy)benzoate.The degree of modification ranged from 48 to 70% depending on the reaction conditions, and the upper value was an apparent modification plateau. NMR characterization indicated that no side reactions of any kind occurred. All copolymers had a nematic columnar mesophase whose range of stability depended on the modification degree. X-ray diffraction experiments showed that the tapered groups were tilted with respect to the column axes. Also X-ray experiments and density measurements demonstrated that the number of disks per unit cell decreased as the modificatuion degree increased. (literal)
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